論文

査読有り
2003年

Laser spectroscopy of silicon quantum materials

Proceedings of SPIE - The International Society for Optical Engineering
  • Yoshihiko Kanemitsu

5024
開始ページ
1
終了ページ
11
記述言語
英語
掲載種別
研究論文(国際会議プロシーディングス)
DOI
10.1117/12.497304

Optical properties and electronic structures of silicon quantum materials are reviewed. Crystalline silicon (c-Si) and amorphous silicon (a-Si) based zero-dimensional (0D) nanoparticles and two-dimensional (2D) quantum-wells were prepared and their photoluminescence (PL) properties were studied by means of resonant excitation spectroscopy. The PL peak energies of c-Si and a-Si nanoparticles and quantum wells are blueshifted from those of bulk c-Si and a-Si. TO-phonon related structures appear in resonantly excited luminescence spectra of H-passivated c-Si and a-Si nanoparticles. This indicates that visible luminescence is due to excitons confined in the interior c-Si and a-Si states. In SiO2-passivated c-Si and a-Si nanoparticles, fine structures due to Si-O-Si vibrations appear in resonant luminescence spectra. In 0D Si/SiO2 systems, excitons are localized at the interface between the Si interior and surface SiO2 layer. In 2D Si/SiO2 systems, both excitons confined in the Si well and excitons localized at the Si-SiO2 interface determine PL properties. The electronic structures and luminescence properties of Si nanostructures are discussed.

リンク情報
DOI
https://doi.org/10.1117/12.497304
ID情報
  • DOI : 10.1117/12.497304
  • ISSN : 0277-786X
  • SCOPUS ID : 0043128520

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