Papers

Peer-reviewed
Aug, 2009

Evidence for oxygen holes due to d-p rehybridization in thermoelectric Sr1-xRh2O4

PHYSICAL REVIEW B
  • Y. Ishida
  • T. Baba
  • R. Eguchi
  • M. Matsunami
  • M. Taguchi
  • A. Chainani
  • Y. Senba
  • H. Ohashi
  • Y. Okamoto
  • H. Takagi
  • S. Shin
  • Display all

Volume
80
Number
8
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1103/PhysRevB.80.081103
Publisher
AMER PHYSICAL SOC

Soft-x-ray photoemission and absorption spectroscopies are employed to investigate the electronic structures of Sr1-xRh2O4. Similar to the layered cobaltates such as Na1-xCoO2, a valence-band satellite feature (VBS) occurs at higher binding energy to the O 2p band. We find that the VBS resonates at the O 1s edge. Additionally, core absorption shows clear x dependence in the O 1s edge rather than in the Rh 3p edge. These results indicate that the holes in the initial state mainly have O 2p character presumably due to d-p rehybridizations affected by Sr2+ vacancy potentials. The resultant inhomogeneous charge texture may have impact on the thermoelectric transport properties at low x.

Link information
DOI
https://doi.org/10.1103/PhysRevB.80.081103
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000269639300003&DestApp=WOS_CPL
ID information
  • DOI : 10.1103/PhysRevB.80.081103
  • ISSN : 2469-9950
  • eISSN : 2469-9969
  • Web of Science ID : WOS:000269639300003

Export
BibTeX RIS