2007年10月
Electronic structure of LaNiO(3-x): An in situ soft x-ray photoemission and absorption study
PHYSICAL REVIEW B
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- 巻
- 76
- 号
- 15
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1103/PhysRevB.76.155104
- 出版者・発行元
- AMER PHYSICAL SOC
We study the electronic structure of LaNiO(3-x) thin films using in situ soft x-ray photoemission and absorption spectroscopy. The in situ high-resolution measurements reveal that states at and near the Fermi level (E(F)) in the occupied and unoccupied densities of states are very sensitive to the oxygen content and are directly related to a metal-insulator transition. The highest quality epitaxial films of LaNiO(3) show a temperature-dependent sharp peak at E(F). A detailed analysis of its electrical resistivity confirms a T(1.5) behavior over a large temperature range, which has been observed in earlier studies. Local density approximation band structure calculations indicate that the narrowing of the Ni d e(g) electron derived peak at E(F) cannot be reproduced by a strained crystal structure, suggesting a renormalization of electronic states at E(F) in LaNiO(3). The T-dependent spectral changes at E(F), coupled with the resistivity behavior and proximity to a metal-insulator transition, suggest the role of electron correlations in LaNiO(3).
- リンク情報
- ID情報
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- DOI : 10.1103/PhysRevB.76.155104
- ISSN : 1098-0121
- Web of Science ID : WOS:000250620400036