Early-phase optical spectra of aspherical jet-like supernovae ( SNe) are presented. We focus on energetic core-collapse SNe, or hypernovae. Based on hydrodynamic and nucleosynthetic models, radiative transfer in the SN atmosphere is solved with a multidimensional Monte Carlo radiative transfer code, SAMURAI. Since the luminosity is boosted in the jet direction, the temperature there is higher than in the equatorial plane by similar to 2000 K. This causes anisotropic ionization in the ejecta. Emergent spectra are different depending on viewing angle, reflecting both aspherical abundance distribution and anisotropic ionization. Spectra computed with an aspherical explosion model with kinetic energy 20 x 10(51) ergs are compatible with those of the Type Ic SN 1998bw if similar to 10%-20% of the synthesized metals are mixed out to higher velocities. The simulations enable us to predict the properties of off-axis hypernovae. Even if an aspherical hypernova explosion is observed from the side, it should show hypernova-like spectra but with some differences in the line velocity, the width of the Fe absorptions, and the strength of the Na I line.