論文

2021年7月

Chemical stability of hydrogen boride nanosheets in water

Communications Materials
  • Kurt
  • Irvin Rojas
  • Nguyen, Thanh Cuong
  • Hiroaki, Nishino
  • Ryota, Ishibiki
  • Shin-ichi, Ito
  • Masahiro, Miyauchi
  • Yoshitaka, Fujimoto
  • Satoshi, Tominaka
  • Susumu, Okada
  • Hideo, Hosono
  • Nelson Jr
  • Arboleda
  • 近藤, 剛弘
  • Yoshitada, Morikawa
  • Ikutaro, Hamada
  • 全て表示

2
1
開始ページ
81
終了ページ
記述言語
日本語
掲載種別
研究論文(学術雑誌)
DOI
10.1038/s43246-021-00184-5
出版者・発行元
Nature publishing group

Boron-based two-dimensional materials are of interest for use in electronic devices and catalytic applications, for which it is important that they are chemically stable. Here, we explore the chemical stability of hydrogen boride nanosheets in water. Experiments reveal that mixing hydrogen boride and water produces negligible amounts of hydrogen, suggesting that hydrolysis does not occur and that hydrogen boride is stable in water, which is in contrast to most boron hydride materials. First-principles calculations reveal that the sheets interact weakly with water even in the presence of defects and that negatively charged boron prevents the onset of hydrolysis. We conclude that the charge state of boron and the covalent boron-boron bond network are responsible for the chemical and structural stability. On the other hand, we found that proton exchange with hydrogen boride nanosheets does occur in water, indicating that they become acidic in the presence of water. Nanoscale boron-based materials are promising for electronic devices, and it is important to understand their chemical stability. Here, hydrogen boride nanosheets are stable against hydrolysis in water, which ab initio calc

リンク情報
DOI
https://doi.org/10.1038/s43246-021-00184-5
URL
http://www.nature.com/articles/s43246-021-00184-5.pdf
URL
http://www.nature.com/articles/s43246-021-00184-5
ID情報
  • DOI : 10.1038/s43246-021-00184-5
  • ISSN : 2662-4443
  • eISSN : 2662-4443

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