2017年
Electrical conduction and thermoelectric properties of tetrathiafulvalene-tetracyanoquinodimethane cast films prepared with N,N-dimethylacetamide
Synthetic Metals
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- 巻
- 230
- 号
- 開始ページ
- 12
- 終了ページ
- 17
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.synthmet.2017.05.013
- 出版者・発行元
- ELSEVIER SCIENCE SA
We evaluated the effect of an amide compound bearing methyl groups on the properties of tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ) cast films. The spontaneous electron transfer between N,N-dimethylacetamide (DMA) and the TCNQ complex is expected to change the casting condition. Then, we obtained a higher density of nanofibers in TTF-TCNQ films using DMA. The electrical conduction of TTF-TCNQ films using DMA was 58.0 S/cm, which is twice that of previously reported polycrystalline films. We measured the Seebeck coefficients of the films for their future possible use as thermoelectric materials. The Seebeck coefficient and power factor of the films prepared with DMA were 32.3 mu V/K and 6.05 mu W/mK2, respectively.
- リンク情報
- ID情報
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- DOI : 10.1016/j.synthmet.2017.05.013
- ISSN : 0379-6779
- ORCIDのPut Code : 45703043
- Web of Science ID : WOS:000405766200003