2002年11月
Highly efficient green up-conversion luminescence of Nd3+-Yb3+-Ho3+ codoped fluorite-type nanocrystals in transparent glass ceramics
JOURNAL OF APPLIED PHYSICS
- ,
- ,
- 巻
- 92
- 号
- 9
- 開始ページ
- 5163
- 終了ページ
- 5168
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1063/1.1508423
- 出版者・発行元
- AMER INST PHYSICS
Oxyfluoride glasses were developed with composition 30SiO(2).15AlO(1.5).28PbF(2).22CdF(2).(4.8-x)GdF3.0.1NdF(3).0.1HoF(3).xYbF(3) (x=0, 0.1, 0.2, 0.5, 1, 2, 3, 4, and 4.8) in mole percent. Powder x-ray diffraction analysis revealed that the heat treatments of the oxyfluoride glasses at 450 degreesC for 0.5 h cause the precipitation of Nd3+-Yb3+-Ho3+ codoped fluorite-type nanocrystals of about 16.3 nm in diameter in the glass matrix. These transparent glass ceramics exhibited very strong green up-conversion luminescence due to the Ho3+: (F-5(4), S-5(2))-->I-5(8) transition under 800 nm excitation. The intensity of the green up-conversion luminescence in a 1 mol % YbF3-containing glass ceramic was found to be about 120 times stronger than that in the precursor oxyfluoride glass. The reason for the highly efficient Ho3+ up-conversion luminescence in the oxyfluoride glass ceramics is discussed. An up-conversion mechanism is also proposed. (C) 2002 American Institute of Physics.
- リンク情報
- ID情報
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- DOI : 10.1063/1.1508423
- ISSN : 0021-8979
- Web of Science ID : WOS:000178767200045