2008年7月
Fluorescence response of a 4-trifluoroacetylaminophthalimide to iodide ions upon 254 nm irradiation in MeCN
ORGANIC LETTERS
- ,
- ,
- ,
- 巻
- 10
- 号
- 14
- 開始ページ
- 3125
- 終了ページ
- 3128
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ol801184x
- 出版者・発行元
- AMER CHEMICAL SOC
The title trifluoroacetylaminophthalimide derivative produced a violet fluorescence (lambda(FL)(max) 392 nm) in MeCN, and it displayed a green emission (lambda(FL)(max) 506 nm) after irradiation at 254 nm in the presence of iodide ions. The corresponding amidate ion of the trifluoroacetamide was identified as the green fluorescence emitter. The deprotonation reaction may be caused by proton-abstracting solvated electrons generated by a photochemical charge-transfer-to-solvent process from I(-) to MeCN.
- リンク情報
- ID情報
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- DOI : 10.1021/ol801184x
- ISSN : 1523-7060
- Web of Science ID : WOS:000257629200053