河内敦 (KAWACHI ATSUSHI) - マイポータル

基本情報

所属: 法政大学生命科学部環境応用化学科教授

学位: 博士（工学）(京都大学)

研究者番号: 70260619
J-GLOBAL ID: 200901050567992549
researchmap会員ID: 5000020939

主要な研究キーワード

もっとみる

主要な研究分野

もっとみる

経歴

学歴

委員歴

2006年4月 - 現在

ケイ素化学協会, ケイ素化学協会理事

受賞

2001年3月

平成12年度日本化学会進歩賞, 日本化学会
2000年11月

第5回ケイ素化学協会奨励賞, ケイ素化学協会

論文

Synthesis of Silicon-Functionalized Dibenzosilaborins by Intramolecular B-H/C-H Dehydrogenative Cyclization and Their Tunable Photophysical and Chemical Properties by Silyl Groups

Atsushi Kawachi, Hiroshi Morisaki, Tatsuya Hirofuji, Yohsuke Yamamoto

CHEMISTRY-A EUROPEAN JOURNAL 19(40) 13294-13298 2013年9月査読有り
Countercation Effect on Reactivity of o-(Fluorodimethylsilyl)phenyl Anion

Atsushi Kawachi, Takuya Teranishi, Takuma Deguchi, Yohsuke Yamamoto

HETEROATOM CHEMISTRY 24(1) 53-57 2013年査読有り
Intramolecular H–Ar Ligand Exchange between Silicon and Boron: Functionality Transfer of Si-H to B-H

Hiroshi Morisaki, Norimasa Nishioka, Yohsuke Yamamoto

Chem. Asian J.. 7(3) 546-553 2012年3月査読有り
Mechanism of Dehydrogenative Condensation of (o-Borylphenyl)hydrosilanes with Methanol

László Könczöl, Atsushi Kawachi, Dénes Szieberth

Organometallics 31(1) 120-126 2012年査読有り
Ortho Magnesiation of Boron-substituted Benzenes by Using (TMP)2Mg

Saori Nagae, Yasuhiro Onoue, Osamu Harada, Yohsuke Yamamoto

Ortho Magnesiation of Boron-substituted Benzenes by Using (TMP)2Mg 17(29) 8005-8008 2011年査読有り
Reaction of o-(HSiR2)(BMes2)C6H4 with a Fluoride Ion: Fluoride Attack at Silicon and Hydride Transfer from Silicon to Boron to Form F–Si•••H–B Interaction

Hiroshi Morisaki, Atsushi Tani, Masatoshi Zaima, Yohsuke Yamamoto

Heteroatom Chem 22(3-4) 471-475 2011年
Synthesis and structures of o-(dihydrosilyl)(dimesitylboryl)benzenes

Atsushi Kawachi, Hiroshi Morisaki, Masatoshi Zaima, Takuya Teranishi, Yohsuke Yamamoto

JOURNAL OF ORGANOMETALLIC CHEMISTRY 695(19-20) 2167-2171 2010年9月査読有り
Synthesis, structure and reactions of triarylgermyl anion with α, δ-ambiphilic character

Koji Machida, Yohsuke Yamamoto

Chem. Commun. 46(11) 1890-1892 2010年
Synthesis of silicon-functionalized 7-silanorbornadienes and their thermolysis and photolysis

Masahiro Okimoto, Atsushi Kawachi, Yohsuke Yamamoto

JOURNAL OF ORGANOMETALLIC CHEMISTRY 694(9-10) 1419-1426 2009年4月査読有り
Preparation and oxidative coupling of bis[o-(hydrosilyl)phenyl]cuprates and bis[o-(fluorosilyl)phenyl]cuprates

Atsushi Kawachi, Takuya Teranishi, Yohsuke Yamamoto

TETRAHEDRON LETTERS 50(11) 1226-1228 2009年3月査読有り
Reactions of [o-(Fluorodimethylsilyl)phenyl]lithium with GeCl2 and SnCl2: Preparation of Poly-functionalized 4-Membered and 5-Membered Cyclic Linkages of Heavier Group 14 Elements

Koji Machida, Yohsuke Yamamoto

Organometallics 28(21) 6347-6351 2009年査読有り
Synthesis and Electronic Spectra of Disilatriptycene Oligomers: Evidence for Electronic Delocalization along the One-Dimensional Arrangement of Bridge-Head Disilanes

Shohei Sase, Yoen-Seok Cho, Atsushi Kawachi, Atsushi Wakamiya, Shigehiro Yamaguchi, Hayato Tsuji, Kohei Tamao

ORGANOMETALLICS 27(21) 5441-5445 2008年11月査読有り
Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

J. Am. Chem. Soc. 130(13) 2008年査読有り
Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

J. Am. Chem. Soc. 130(13) 2008年査読有り
Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

J. Am. Chem. Soc. 130(13) 2008年査読有り
Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Synthesis of B, Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, d Their Fluoride Ion Affinity

J. Am. Chem. Soc. 130(13) 2008年査読有り
Intramolecular Reaction of Silanol and Triarylborane: Boron–Aryl Bond Cleavage and Formation of a Si-O-B Heterocyle

Masatoshi Zaima, Yohsuke Yamamoto

Organometallics 27(18) 2008年査読有り
Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Synthesis of B, Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, d Their Fluoride Ion Affinity

J. Am. Chem. Soc. 130(13) 2008年査読有り

書籍等出版物

有機ケイ素化学

吉良満夫,玉尾皓平編 (担当:分担執筆)

化学同人 2013年6月
使える！有機合成反応241 実践ガイド

丸岡啓二,野崎京子,石井康敬,大寺純蔵,富岡清編 (担当:分担執筆)

化学同人 2010年4月

講演・口頭発表等

Development of Monolithio- and Dilithioarenes Bearing Functionalized Silyl Groups Directed toward Synthesis of Silicon-containing Ladder Polymers

Atsushi Nakamoto, Yohsuke Yamamoto

The 10th International Symposium on Carbanion Chemistry 2013年9月23日
Formation, Structures and Reactions of Silicon-Functionalized Dibenzosilaborins

Tatsuya Hirofuji, Hiroshi Morisaki, Atsushi Kawachi, Yohsuke Yamamoto

4th Asian Silicon Symposium 2012年10月21日
Formation, Structures, and Reactions of Dibenzosilaborins

Atushi Kawachi, Hiroshi Morisaki, Tatsuya Hirofuji, Yukihiro Ueki, Yohsuke Yamamoto

The 10th International Conference on Heteroatom Chemistry 2012年5月20日
Ortho Magnesiation of Boron-substituted Benzenes Using (TMP)2Mg

Osamu Harada, Saori Nagae, Yohsuke Yamamoto

1st International Symposium on Molecular Activation 2011年9月9日
H–Ar Ligand Exchange between Silicon and Boron in o-(Hydrosilyl)(diarylboryl)benzenes and Subsequent Intramolecular Cyclization: Formation of Dibenzosilaborins

Hiroshi Morisaki, Yohsuke Yamamoto

16th International Symposium on Silicon Chemistry 2011年8月14日
Ortho Magnesiation of Boron-substituted Benzenes Using (TMP)2Mg

Saori Nagae, Yasuhiro Onoue, Yohsuke Yamamoto

9th International Symposium on Carbanion Chemistry 2010年7月20日
Synthesis and Reactions of o-Dihydrosilyl(dimesitylboryl)benzenes

Hiroshi Morisaki, Yohsuke Yamamoto

The 4th Hiroshima Workshop on Sustainable Material Science 2009年11月13日
[o-(Fluorosilyl)phenyl]lithium: A Useful Tool for Functionalizing Main Group Element Compounds

The 4th International Symposium for Young Elements Chemists, 2009 Workshop on Organometallic Chemistry 2009年10月28日
Synthesis, Structure, and Reaction of {Tris[o-(fluorodimethylsilyl)phenyl]germyl}potassium

Koji Machida, Yohsuke Yamamoto

9th International Conference on Heteroatom Chemistry 2009年6月30日
Dehydrogenative Condensation of (o-Borylphenyl)hydrosilane with Alcohols and Amines

Second Japan-Singapore Bilateral Symposium on Catalysis 2009年1月6日

所属学協会

2002年4月 - 現在

近畿化学協会
2002年4月 - 現在

合成化学協会
2001年9月 - 現在

アメリカ化学会
1993年11月 - 現在

ケイ素化学協会
1990年4月 - 現在

日本化学会