KAWACHI ATSUSHI - My portal

Profile Information

Affiliation: Professor, Faculty of Bioscience and Applied Chemistry, Department of Chemical Science and Technology, Hosei University

Degree: 博士（工学）(京都大学)

Researcher number: 70260619
J-GLOBAL ID: 200901050567992549
researchmap Member ID: 5000020939

Major Research Interests

Major Research Areas

Research History

Apr, 2007 - Mar, 2012

広島大学大学院理学研究科化学専攻・准教授
Apr, 2006 - Mar, 2008

広島大学先進機能物質研究センター研究員
Feb, 2002 - Mar, 2007

広島大学大学院理学研究科化学専攻・助教授
Nov, 1993 - Jan, 2002

京都大学化学研究所助手
Apr, 1993 - Oct, 1993

日本学術振興会特別研究員
Apr, 1993 - Oct, 1993

日本学術振興会特別研究員

Education

Apr, 1992 - Oct, 1993

Department of Synthetic Chemistry, Graduate School, Division of Engineering, Kyoto University
Apr, 1992 - Oct, 1993

Department of Synthetic Chemistry, Graduate School, Division of Engineering, Kyoto University
Apr, 1990 - Mar, 1992

Department of Synthetic Chemistry, Graduate School, Division of Engineering, Kyoto University
Apr, 1990 - Mar, 1992

Department of Synthetic Chemistry, Graduate School, Division of Engineering, Kyoto University
Apr, 1986 - Mar, 1990

Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University

Committee Memberships

Apr, 2006 - Present

ケイ素化学協会理事, ケイ素化学協会

Awards

Mar, 2001

平成12年度日本化学会進歩賞, 日本化学会
Nov, 2000

第5回ケイ素化学協会奨励賞, ケイ素化学協会

Papers

Synthesis of Silicon-Functionalized Dibenzosilaborins by Intramolecular B-H/C-H Dehydrogenative Cyclization and Their Tunable Photophysical and Chemical Properties by Silyl Groups

Atsushi Kawachi, Hiroshi Morisaki, Tatsuya Hirofuji, Yohsuke Yamamoto

CHEMISTRY-A EUROPEAN JOURNAL, 19(40) 13294-13298, Sep, 2013 Peer-reviewed
Countercation Effect on Reactivity of o-(Fluorodimethylsilyl)phenyl Anion

Atsushi Kawachi, Takuya Teranishi, Takuma Deguchi, Yohsuke Yamamoto

HETEROATOM CHEMISTRY, 24(1) 53-57, 2013 Peer-reviewed
Intramolecular H-Ar Ligand Exchange between Silicon and Boron: Functionality Transfer of Si-H to B-H

Atsushi Kawachi, Hiroshi Morisaki, Norimasa Nishioka, Yohsuke Yamamoto

CHEMISTRY-AN ASIAN JOURNAL, 7(3) 546-553, Mar, 2012 Peer-reviewed
Mechanism of Dehydrogenative Condensation of (o-Borylphenyl)hydrosilanes with Methanol

László Könczöl, Atsushi Kawachi, Dénes Szieberth

Organometallics, 31(1) 120-126, 2012 Peer-reviewed
Ortho Magnesiation of Boron-substituted Benzenes by Using (TMP)2Mg

Saori Nagae, Yasuhiro Onoue, Osamu Harada, Yohsuke Yamamoto

Ortho Magnesiation of Boron-substituted Benzenes by Using (TMP)2Mg, 17(29) 8005-8008, 2011 Peer-reviewed
Reaction of o-(HSiR2)(BMes(2))C6H4 with a Fluoride Ion: Fluoride Attack at Silicon and Hydride Transfer from Silicon to Boron to Form F-Si center dot center dot center dot H-B Interaction

Atsushi Kawachi, Hiroshi Morisaki, Atsushi Tani, Masatoshi Zaima, Yohsuke Yamamoto

HETEROATOM CHEMISTRY, 22(3-4) 471-475, 2011
Synthesis and structures of o-(dihydrosilyl)(dimesitylboryl)benzenes

Atsushi Kawachi, Hiroshi Morisaki, Masatoshi Zaima, Takuya Teranishi, Yohsuke Yamamoto

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 695(19-20) 2167-2171, Sep, 2010 Peer-reviewed
Synthesis, structure and reactions of triarylgermyl anion with alpha,delta-ambiphilic character

Atsushi Kawachi, Koji Machida, Yohsuke Yamamoto

CHEMICAL COMMUNICATIONS, 46(11) 1890-1892, 2010
Synthesis of silicon-functionalized 7-silanorbornadienes and their thermolysis and photolysis

Masahiro Okimoto, Atsushi Kawachi, Yohsuke Yamamoto

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 694(9-10) 1419-1426, Apr, 2009 Peer-reviewed
Preparation and oxidative coupling of bis[o-(hydrosilyl)phenyl]cuprates and bis[o-(fluorosilyl)phenyl]cuprates

Atsushi Kawachi, Takuya Teranishi, Yohsuke Yamamoto

TETRAHEDRON LETTERS, 50(11) 1226-1228, Mar, 2009 Peer-reviewed
Reactions of [o-(Fluorodimethylsilyl)phenyl]lithium with GeCl2 and SnCl2: Preparation of Poly-functionalized 4-Membered and 5-Membered Cyclic Linkages of Heavier Group 14 Elements

Koji Machida, Yohsuke Yamamoto

Organometallics, 28(21) 6347-6351, 2009 Peer-reviewed
Synthesis and Electronic Spectra of Disilatriptycene Oligomers: Evidence for Electronic Delocalization along the One-Dimensional Arrangement of Bridge-Head Disilanes

Shohei Sase, Yoen-Seok Cho, Atsushi Kawachi, Atsushi Wakamiya, Shigehiro Yamaguchi, Hayato Tsuji, Kohei Tamao

ORGANOMETALLICS, 27(21) 5441-5445, Nov, 2008 Peer-reviewed
Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

J. Am. Chem. Soc., 130(13), 2008 Peer-reviewed
Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

J. Am. Chem. Soc., 130(13), 2008 Peer-reviewed
Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

J. Am. Chem. Soc., 130(13), 2008 Peer-reviewed
Intramolecular Reaction of Silanol and Triarylborane: Boron–Aryl Bond Cleavage and Formation of a Si-O-B Heterocyle

Masatoshi Zaima, Yohsuke Yamamoto

Organometallics, 27(18), 2008 Peer-reviewed
Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Synthesis of B, Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, d Their Fluoride Ion Affinity

J. Am. Chem. Soc., 130(13), 2008 Peer-reviewed

Books and Other Publications

有機ケイ素化学

吉良満夫, 玉尾皓平編 (Role: Contributor)

化学同人, Jun, 2013
使える！有機合成反応241 実践ガイド

丸岡啓二, 野崎京子, 石井康敬, 大寺純蔵, 富岡清編 (Role: Contributor)

化学同人, Apr, 2010

Presentations

Development of Monolithio- and Dilithioarenes Bearing Functionalized Silyl Groups Directed toward Synthesis of Silicon-containing Ladder Polymers

Atsushi Nakamoto, Yohsuke Yamamoto

The 10th International Symposium on Carbanion Chemistry, Sep 23, 2013
Formation, Structures and Reactions of Silicon-Functionalized Dibenzosilaborins

Tatsuya Hirofuji, Hiroshi Morisaki, Atsushi Kawachi, Yohsuke Yamamoto

4th Asian Silicon Symposium, Oct 21, 2012
Formation, Structures, and Reactions of Dibenzosilaborins

Atushi Kawachi, Hiroshi Morisaki, Tatsuya Hirofuji, Yukihiro Ueki, Yohsuke Yamamoto

The 10th International Conference on Heteroatom Chemistry, May 20, 2012
Ortho Magnesiation of Boron-substituted Benzenes Using (TMP)2Mg

Osamu Harada, Saori Nagae, Yohsuke Yamamoto

1st International Symposium on Molecular Activation, Sep 9, 2011
H–Ar Ligand Exchange between Silicon and Boron in o-(Hydrosilyl)(diarylboryl)benzenes and Subsequent Intramolecular Cyclization: Formation of Dibenzosilaborins

Hiroshi Morisaki, Yohsuke Yamamoto

16th International Symposium on Silicon Chemistry, Aug 14, 2011
Ortho Magnesiation of Boron-substituted Benzenes Using (TMP)2Mg

Saori Nagae, Yasuhiro Onoue, Yohsuke Yamamoto

9th International Symposium on Carbanion Chemistry, Jul 20, 2010
Synthesis and Reactions of o-Dihydrosilyl(dimesitylboryl)benzenes

Hiroshi Morisaki, Yohsuke Yamamoto

The 4th Hiroshima Workshop on Sustainable Material Science, Nov 13, 2009
[o-(Fluorosilyl)phenyl]lithium: A Useful Tool for Functionalizing Main Group Element Compounds

The 4th International Symposium for Young Elements Chemists, 2009 Workshop on Organometallic Chemistry, Oct 28, 2009
Synthesis, Structure, and Reaction of {Tris[o-(fluorodimethylsilyl)phenyl]germyl}potassium

Koji Machida, Yohsuke Yamamoto

9th International Conference on Heteroatom Chemistry, Jun 30, 2009
Dehydrogenative Condensation of (o-Borylphenyl)hydrosilane with Alcohols and Amines

Second Japan-Singapore Bilateral Symposium on Catalysis, Jan 6, 2009

Professional Memberships

Apr, 2002 - Present

近畿化学協会
Apr, 2002 - Present

合成化学協会
Sep, 2001 - Present

アメリカ化学会
Nov, 1993 - Present

ケイ素化学協会
Apr, 1990 - Present

日本化学会