論文

査読有り
2004年4月

Icosahedral quasicrystals in Zn-T-Sc (T = Mn, Fe, Co or Ni) alloys

PHILOSOPHICAL MAGAZINE LETTERS
  • R Maezawa
  • ,
  • S Kashimoto
  • ,
  • T Ishimasa

84
4
開始ページ
215
終了ページ
223
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1080/09500830410001664544
出版者・発行元
TAYLOR & FRANCIS LTD

Starting from the Zn17Sc3 cubic approximant, new quasicrystal alloys were sought by replacement of Zn with transition elements T. In the cases when T = Mn, Fe, Co and Ni, new icosahedral quasicrystals are formed in as-cast alloys as major phases at alloy compositions of Zn75T10Sc15. All these quasicrystals belong to a primitive type and have six-dimensional lattice parameters a(6D) ranging from 7.044 to 7.107 Angstrom. They have valence electron concentrations e/a ranging from 2.01 to 2.14, and almost the same ratios between the edge length a(R) of the Penrose tile and the averaged atomic diameter (d) over bar :a(R)/d approximate to 1.76. Moreover other Zn- and Cd-based quasicrystals, including the same type of atomic Tsai-type cluster, have the same values of e/a approximate to 2.1 and a(R)/(d) over bar approximate to 1.75 The equality in e/a indicates that the Hume-Rothery mechanism plays an important role for the formation of these quasicrystals.

リンク情報
DOI
https://doi.org/10.1080/09500830410001664544
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000220127900002&DestApp=WOS_CPL
ID情報
  • DOI : 10.1080/09500830410001664544
  • ISSN : 0950-0839
  • Web of Science ID : WOS:000220127900002

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