2019年
Molecular diamond lattice antiferromagnet as a Dirac semimetal candidate
Physical Review B
- ,
- ,
- ,
- ,
- ,
- ,
- ,
- ,
- 巻
- 99
- 号
- 17
- 開始ページ
- 174417
- 終了ページ
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1103/PhysRevB.99.174417
- 出版者・発行元
- AMER PHYSICAL SOC
The ground state of a molecular diamond lattice compound (ET)Ag-4(CN)(5) is investigated by magnetization and nuclear magnetic resonance spectroscopy. We found that the material exhibits a Mott-insulating ground state with antiferromagnetic long-range ordering at 102 K. The ordered moment shows weak ferromagnetism with a tiny canting angle. The spin susceptibility is well fitted into the diamond lattice Heisenberg model with a nearest-neighbor exchange coupling of 230 K, indicating the less frustrated interactions. The transition temperature elevates up to similar to 195 K by applying pressure of 2 GPa, which records the highest temperature among organic molecular magnets. The first-principles band calculation without electron correlations suggests that the system is accessible to a three-dimensional topological semimetal with nodal Dirac lines, which has been anticipated on a half-filling diamond lattice.
- リンク情報
-
- DOI
- https://doi.org/10.1103/PhysRevB.99.174417
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000469051100008&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-85066404319&partnerID=MN8TOARS
- ID情報
-
- DOI : 10.1103/PhysRevB.99.174417
- ISSN : 2469-9969
- eISSN : 2469-9969
- ORCIDのPut Code : 71769880
- SCOPUS ID : 85066404319
- Web of Science ID : WOS:000469051100008