論文

査読有り
2016年12月

Transparent Ethylene-Bridged Polymethylsiloxane Aerogels and Xerogels with Improved Bending Flexibility

LANGMUIR
  • Taiyo Shimizu
  • ,
  • Kazuyoshi Kanamori
  • ,
  • Ayaka Maeno
  • ,
  • Hironori Kaji
  • ,
  • Kazuki Nakanishi

32
50
開始ページ
13427
終了ページ
13434
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/acs.langmuir.6b03249
出版者・発行元
AMER CHEMICAL SOC

Transparent, monolithic aerogels with nano sized colloidal skeletons have been obtained from a single precursor of 1,2-bis(methyldiethoxysilyl)ethane (BMDEE) by adopting a liquid surfactant and a two-step process involving strong-acid, followed by strong-base, sol gel reactions. This precursor BMDEE forms the ethylene-bridged polymethylsiloxane (EBPMS, O-2/2(CH3)Si-CH2CH2-Si(CH3)O-2/2) network, in which each silicon has one methyl, two bridging oxygens, and one bridging ethylene, exhibiting an analogous structure to that of the previously reported polymethylsilsesquioxane (PMSQ CH3SiO3/2) aerogels having one methyl and three bridging oxygen atoms. Obtained aerogels consist of fine colloidal skeletons and show high visible-light transparency and a flexible deformation behavior against compression without collapse. Similar to the PMSQ aerogels, a careful tuning of synthetic conditions can produce low-density (0.19 g cm(-3)) and highly transparent (76% at 550 nm, corresponding to 10 mm thick samples) xerogels via ambient pressure drying by solvent evaporation due to their high strength and resilience against compression. Moreover, EBPMS aerogels exhibit higher bending strength and bending strain at break against the three-point bending mode compared to PMSQ aerogels. This improved bendability is presumably derived from the introduced ethylene-bridging parts, suggesting the potential for realizing transparent and bendable aerogels in such polysiloxane materials with organic linking units.

リンク情報
DOI
https://doi.org/10.1021/acs.langmuir.6b03249
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/27993023
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000390619900015&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/acs.langmuir.6b03249
  • ISSN : 0743-7463
  • PubMed ID : 27993023
  • Web of Science ID : WOS:000390619900015

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