2013年9月10日
Hierarchically porous monoliths based on N-doped reduced titanium oxides and their electric and electrochemical properties
Chemistry of Materials
- ,
- ,
- ,
- ,
- ,
- ,
- ,
- ,
- 巻
- 25
- 号
- 17
- 開始ページ
- 3504
- 終了ページ
- 3512
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/cm401933a
In this report, we demonstrate a novel synthesis method to obtain reduced titanium oxides with monolithic shape and with a well-defined hierarchically porous structure from the titanium-based network bridged with ethylenediamine. The hierarchically porous monoliths are fabricated by the nonhydrolytic sol-gel reaction accompanied by phase separation. This method allows a low-temperature crystallization into Ti4O7 and Ti3O5 at 800 and 900 C, respectively, with N-doped carbon. These reduced titanium oxides are well-doped with N atoms even under argon atmosphere without NH 3, which accounts for the low-temperature reduction. The resultant monolithic materials possess controllable macropores and high specific surface area together with excellent electric conductivity up to 230 S cm-1, indicating promise as a conductive substrate that can substitute carbon electrodes. © 2013 American Chemical Society.
- リンク情報
-
- DOI
- https://doi.org/10.1021/cm401933a
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201302229792056883
- URL
- http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000330097900013&KeyUID=WOS:000330097900013
- URL
- http://orcid.org/0000-0001-5087-9808
- ID情報
-
- DOI : 10.1021/cm401933a
- ISSN : 0897-4756
- ISSN : 1520-5002
- J-Global ID : 201302229792056883
- ORCIDのPut Code : 25791998
- SCOPUS ID : 84884198786
- ORCIDで取得されたその他外部ID : a:1:{i:0;a:1:{s:8:"other-id";s:19:"WOS:000330097900013";}}