2012年8月
Para-Bridged Macrocyclic Host Molecules Pillar[5]arenes: Their Synthesis and Application for Supramolecular Materials
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN
- ,
- 巻
- 70
- 号
- 8
- 開始ページ
- 842
- 終了ページ
- 851
- 記述言語
- 日本語
- 掲載種別
- DOI
- 10.5059/yukigoseikyokaishi.70.842
- 出版者・発行元
- SOC SYNTHETIC ORGANIC CHEM JPN
In 2008, we reported a new class of macrocyclic hosts and named "Pillar[5]arenes". They combine the advantages and aspects of traditional hosts and have a composition similar to those of typical calix[n]arenes. Pillar[5]arenes have repeating units connected by methylene bridges at the para-position, and thus they have a unique symmetrical pillar architecture differing from the basket-shaped structure of meta-bridged calix[n]arenes. Pillar[5]arenes show high functionality similar to cyclodextrins, and can capture electron accepting guest molecules within their cavity similarly to cucurbit[n]urils. In this review, the synthesis, structure, rotation, host-guest properties, planar chirality and functionality of pillar[5]arenes are discussed, along with pillar[5]-arene-based supramolecular architectures.
- リンク情報
- ID情報
-
- DOI : 10.5059/yukigoseikyokaishi.70.842
- ISSN : 0037-9980
- ORCIDのPut Code : 25144637
- SCOPUS ID : 84880373147
- Web of Science ID : WOS:000307525200006