2007年9月
A silicon-based approach to oligoarenes by iterative cross-coupling reactions of halogenated organo[(2-hydroxymethyl)phenyl]dimethylsilanes
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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- ,
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- 巻
- 129
- 号
- 38
- 開始ページ
- 11694
- 終了ページ
- +
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja074728s
- 出版者・発行元
- AMER CHEMICAL SOC
Highly efficient synthesis of silyl-substituted oligoarenes with defined structures is achieved by an iterative cross-coupling reaction and deprotection sequence using organo[(2-hydroxymethyl)phenyl]dimethylsilanes. The excellent stability of the tetraorganosilicon compounds as well as mild and divergent conditions for cross-coupling and deprotection steps allows preparation of highly conjugated oligoarenylsilanes such as unsymmetrically disilylated quinquethiophenes.
- リンク情報
- ID情報
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- DOI : 10.1021/ja074728s
- ISSN : 0002-7863
- eISSN : 1520-5126
- Web of Science ID : WOS:000249693800016