MISC

2007年5月

Electrodeposition of silver thin films with shiny appearances from an electrolyte comprising silver ferrocyanide-thiocyanate and antimony potassium tartrate

SURFACE & COATINGS TECHNOLOGY
  • M. Saitou
  • ,
  • I. Ota
  • ,
  • A. Nakano
  • ,
  • S. M. Asadul Hossain

201
16-17
開始ページ
6947
終了ページ
6952
記述言語
英語
掲載種別
DOI
10.1016/j.surfcoat.2006.12.024
出版者・発行元
ELSEVIER SCIENCE SA

We have investigated the effect of antimony potassium tartrate on the surface appearances of silver thin films electrodeposited from a silver ferrocyanide-thiocyanate electrolyte. Phase diagrams of appearance stability in silver electrodeposition indicate that the silver ferrocyanide-thiocyanate electrolyte including antimony potassium tartrate yields silver electrodeposits with shiny appearances within a narrow region of the cathode potential. The surface roughness of the electrodeposits measured with Confocal Laser Scanning Microscopy reveals that the shiny appearance corresponds to two-dimensional growth that results in a smooth surface and the black appearance does to three-dimensional growth characterized by vertical growth. Cyclic voltammetry curves exhibit that the shiny appearances can be related to a rapid increase in the current density at the narrow region of the cathode potential. (C) 2007 Published by Elsevier B.V.

リンク情報
DOI
https://doi.org/10.1016/j.surfcoat.2006.12.024
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000246509800007&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.surfcoat.2006.12.024
  • ISSN : 0257-8972
  • Web of Science ID : WOS:000246509800007

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