2007年5月
Electrodeposition of silver thin films with shiny appearances from an electrolyte comprising silver ferrocyanide-thiocyanate and antimony potassium tartrate
SURFACE & COATINGS TECHNOLOGY
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- ,
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- 巻
- 201
- 号
- 16-17
- 開始ページ
- 6947
- 終了ページ
- 6952
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/j.surfcoat.2006.12.024
- 出版者・発行元
- ELSEVIER SCIENCE SA
We have investigated the effect of antimony potassium tartrate on the surface appearances of silver thin films electrodeposited from a silver ferrocyanide-thiocyanate electrolyte. Phase diagrams of appearance stability in silver electrodeposition indicate that the silver ferrocyanide-thiocyanate electrolyte including antimony potassium tartrate yields silver electrodeposits with shiny appearances within a narrow region of the cathode potential. The surface roughness of the electrodeposits measured with Confocal Laser Scanning Microscopy reveals that the shiny appearance corresponds to two-dimensional growth that results in a smooth surface and the black appearance does to three-dimensional growth characterized by vertical growth. Cyclic voltammetry curves exhibit that the shiny appearances can be related to a rapid increase in the current density at the narrow region of the cathode potential. (C) 2007 Published by Elsevier B.V.
- リンク情報
- ID情報
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- DOI : 10.1016/j.surfcoat.2006.12.024
- ISSN : 0257-8972
- Web of Science ID : WOS:000246509800007