2005年9月
Ion-induced nucleation in polar one-component fluids
JOURNAL OF CHEMICAL PHYSICS
- ,
- 巻
- 123
- 号
- 12
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1063/1.2039078
- 出版者・発行元
- AMER INST PHYSICS
We present a Ginzburg-Landau theory of ion-induced nucleation in a gas phase of polar one-component fluids, where a liquid droplet grows with an ion at its center. By calculating the density profile around an ion, we show that the solvation free energy is larger in gas than in liquid at the same temperature on the coexistence curve. This difference much reduces the nucleation barrier in a metastable gas. (c) 2005 American Institute of Physics.
- リンク情報
- ID情報
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- DOI : 10.1063/1.2039078
- ISSN : 0021-9606
- PubMed ID : 16392503
- Web of Science ID : WOS:000232206500040