2008年
Palladium-mediated Polymerization of Diazoacetamides
POLYMER JOURNAL
- ,
- ,
- ,
- 巻
- 40
- 号
- 11
- 開始ページ
- 1094
- 終了ページ
- 1098
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1295/polymj.PJ2008145
- 出版者・発行元
- SOC POLYMER SCIENCE JAPAN
Palladium-mediated polymerization of diazoacetamides bearing various substituents 1-4 is described. Homopolymerization of monomers with n-hexyl or 4-n-octylphenyl group on the nitrogen afforded polymers [poly(N-substituted carbamoylmethylene)], whose all the main chain carbons have N-substituted carbamoly groups. Elemental analysis of the products indicated incorporation of azo group in the main chain. Copolymerization of diazoacetamides 1-4 with a diazoketone. (E)-1-diazo-4-phenyl-3-buten-2-one 5, proceeded efficiently, giving poly(substituted methylene)s with a variety of N-substituted carbamoyl groups in their side chains.
- リンク情報
- ID情報
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- DOI : 10.1295/polymj.PJ2008145
- ISSN : 0032-3896
- Web of Science ID : WOS:000262247400009