2007年10月
Growth of large (1 mm) MgSiO3 perovskite single crystals: A thermal gradient method at ultrahigh pressure
AMERICAN MINERALOGIST
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- 巻
- 92
- 号
- 10
- 開始ページ
- 1744
- 終了ページ
- 1749
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.2138/am.2007.2415
- 出版者・発行元
- MINERALOGICAL SOC AMER
Large single crystals of MgSiO3 perovskite were successfully synthesized by a thermal gradient method at 24 GPa and 1500 degrees C. This was achieved by an improvement of high-pressure synthesis technique that allowed us to grow single crystals under such ultrahigh-pressure conditions in relatively large volumes (e.g., 10 mm(3)). Since crystal growth is hindered by neighboring crystals, the nucleation density was suppressed by reducing the thermal gradient to 20 degrees C/mm, permitting an increase in free space for large crystal growth. KHCO3-Mg(OH)2 solvent can be used to grow perovskite crystals. However, the carbonate solvent produces melt inclusions. Silicate sources with MgSiO3 composition produce stishovite inclusions, which in turn cause sptitting of perovskite crystals. The formation of these inclusions is avoided by using H2O as a solvent and 85MgSiO(3)-15Mg(2)SiO(4), as a silicate source. The H2O also allows homogeneous crystal growth, probably because of its low viscosity and high silicate solubility. High-quality single crystals larger than I mm were successfully synthesized through these technical developments.
- リンク情報
- ID情報
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- DOI : 10.2138/am.2007.2415
- ISSN : 0003-004X
- eISSN : 1945-3027
- Web of Science ID : WOS:000249968300022