論文

2011年7月

Synthesis and properties of functional π-expanded compounds prepared by thermal or photochemical conversion of the precursors

Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
  • Hiroko Yamada
  • ,
  • Hiroko Yamada
  • ,
  • Daiki Kuzuhara
  • ,
  • Shuhei Katsuta
  • ,
  • Tetsuo Okujima
  • ,
  • Hidemitsu Uno

69
7
開始ページ
802
終了ページ
813
記述言語
日本語
掲載種別
研究論文(学術雑誌)
DOI
10.5059/yukigoseikyokaishi.69.802

This paper focuses on the synthesis of new aromatic compounds by thermal, photochemical, or oxidative cleavage reaction of the corresponding precursors. The precursor-methods are useful for the derivatization of the non-soluble aromatic compounds. We have applied retro Diels-Alder reactions for the preparation of new π-expanded porphyrinoid compounds such as [14]tribenzotriphyrin (2.1.1), tetrabenzoporphycene, dodecasubstituted porphycene, tetraanthraporphyin, butadiyne-linked tetrabenzoporphyrin dimer, and so on. We have investigated the photocleavage synthesis of pentacenes from the corresponding a-diketone precursors. This photoreaction enabled us to prepare 1,4,8,11-tetrasubstituted pentacene. The synthesis of new pentacene derivatives with electron-withdrawing substituents at 6,13-positions by oxidative cleavage reaction will be also reported.

リンク情報
DOI
https://doi.org/10.5059/yukigoseikyokaishi.69.802
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000292627400006&DestApp=WOS_CPL
URL
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=81155134499&origin=inward
ID情報
  • DOI : 10.5059/yukigoseikyokaishi.69.802
  • ISSN : 0037-9980
  • SCOPUS ID : 81155134499
  • Web of Science ID : WOS:000292627400006

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