2011年7月
Synthesis and properties of functional π-expanded compounds prepared by thermal or photochemical conversion of the precursors
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
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- 巻
- 69
- 号
- 7
- 開始ページ
- 802
- 終了ページ
- 813
- 記述言語
- 日本語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.5059/yukigoseikyokaishi.69.802
This paper focuses on the synthesis of new aromatic compounds by thermal, photochemical, or oxidative cleavage reaction of the corresponding precursors. The precursor-methods are useful for the derivatization of the non-soluble aromatic compounds. We have applied retro Diels-Alder reactions for the preparation of new π-expanded porphyrinoid compounds such as [14]tribenzotriphyrin (2.1.1), tetrabenzoporphycene, dodecasubstituted porphycene, tetraanthraporphyin, butadiyne-linked tetrabenzoporphyrin dimer, and so on. We have investigated the photocleavage synthesis of pentacenes from the corresponding a-diketone precursors. This photoreaction enabled us to prepare 1,4,8,11-tetrasubstituted pentacene. The synthesis of new pentacene derivatives with electron-withdrawing substituents at 6,13-positions by oxidative cleavage reaction will be also reported.
- リンク情報
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- DOI
- https://doi.org/10.5059/yukigoseikyokaishi.69.802
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000292627400006&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=81155134499&origin=inward
- ID情報
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- DOI : 10.5059/yukigoseikyokaishi.69.802
- ISSN : 0037-9980
- SCOPUS ID : 81155134499
- Web of Science ID : WOS:000292627400006