Papers

Aug, 2010

Synthesis and properties of BCOD-fused trithiasapphyrin and trithiabenzosapphyrins

TETRAHEDRON
  • Tetsuo Okujima
  • ,
  • Tasuku Kikkawa
  • ,
  • Saori Kawakami
  • ,
  • Yusuke Shimizu
  • ,
  • Hiroko Yamada
  • ,
  • Noboru Ono
  • ,
  • Hidemitsu Uno

Volume
66
Number
35
First page
7213
Last page
7218
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1016/j.tet.2010.06.086
Publisher
PERGAMON-ELSEVIER SCIENCE LTD

Bicyclo[2.2.2]octadiene(BCOD)-fused trithiasapphyrin was prepared by 3+2 condensation of BCOD-fused thiatripyrrane with BCOD-fused bithiophene. The BCOD-fused trithiasapphyrin was successfully converted to pentabenzo[b,g,l,q,v]sapphyrin by the thermal retro-Diels-Alder reaction. In this case, trithiapentabenzo[b,g,l,q,v]- and trithiadibenzo[g,q]sapphyrins were selectively prepared by control of the temperature in the thermal retro-Diels-Alder reaction. (C) 2010 Elsevier Ltd. All rights reserved.

Link information
DOI
https://doi.org/10.1016/j.tet.2010.06.086
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000281298900021&DestApp=WOS_CPL
URL
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=77955429509&origin=inward
ID information
  • DOI : 10.1016/j.tet.2010.06.086
  • ISSN : 0040-4020
  • SCOPUS ID : 77955429509
  • Web of Science ID : WOS:000281298900021

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