Papers

Peer-reviewed
Sep, 2016

Synthesis of hexagonal shape-persistent cyclophane with D-2h symmetry

TETRAHEDRON LETTERS
  • Kazunari Tagawa
  • ,
  • Shigeki Mori
  • ,
  • Masayoshi Takase
  • ,
  • Tetsuo Okujima
  • ,
  • Ichiro Hisaki
  • ,
  • Hidemitsu Uno

Volume
57
Number
36
First page
4079
Last page
4081
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1016/j.tetlet.2016.07.086
Publisher
PERGAMON-ELSEVIER SCIENCE LTD

In this study, hexagonal shape-persistent cyclophane with D-2h symmetry and rigid dihedral angles was obtained through the key SNAr reaction of perfluorobenzene moieties and dipyrroles. The X-ray analysis of the compound thus obtained revealed a hexagonal macrocyclic structure with D-2h symmetry due to the dihedral angles of 120 degrees and double 120 degrees for bicyclo[2.2.2]octadiene:fused dipyrrole and syn-diethanotetrahydroanthracene-fused dipyrrole, respectively. (C) 2016 Elsevier Ltd. All rights reserved.

Link information
DOI
https://doi.org/10.1016/j.tetlet.2016.07.086
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000382338200024&DestApp=WOS_CPL
URL
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84981320700&origin=inward
ID information
  • DOI : 10.1016/j.tetlet.2016.07.086
  • ISSN : 0040-4039
  • SCOPUS ID : 84981320700
  • Web of Science ID : WOS:000382338200024

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