2008年6月
Au(I) complexes-catalyzed transfer vinylation of alcohols and carboxylic acids
TETRAHEDRON LETTERS
- ,
- 巻
- 49
- 号
- 23
- 開始ページ
- 3729
- 終了ページ
- 3732
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1016/j.tetlet.2008.04.037
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
Au(I) complexes-catalyzed transfer vinylation of alcohols and carboxylic acids has been achieved. The catalyst system consists of 2 mol % AuClPPh(3) and 2 mol % AgOAc. Primary alcohols and secondary alcohols were converted into corresponding vinyl ethers in good yield (64-93%); however, tertiary alcohols showed poor reactivities. Carboxylic acids were also transformed into corresponding vinyl esters in good yield (78-96%). (C) 2008 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
-
- DOI : 10.1016/j.tetlet.2008.04.037
- ISSN : 0040-4039
- Web of Science ID : WOS:000256378800006