論文

2005年4月

Determination of a merocyanine J-aggregate structure and the significant contribution of the electric dipole interaction to the exciton band wavelength

PHYSICAL REVIEW LETTERS
  • N Kato
  • ,
  • K Yuasa
  • ,
  • T Araki
  • ,
  • Hirosawa, I
  • ,
  • M Sato
  • ,
  • N Ikeda
  • ,
  • K Iimura
  • ,
  • Y Uesu

94
13
開始ページ
pp136404 1-136404 4
終了ページ
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1103/PhysRevLett.94.136404
出版者・発行元
AMER PHYSICAL SOC

The molecular alignment of a merocyanine (MC) J-aggregate monolayer at the air-water interface was determined by a grazing incidence x-ray diffraction method. The obtained molecular arrangement apparently shows that the conventional formula, which accounts only for the transition dipole interaction, is not sufficient to figure out the exciton band wavelength, suggesting the importance of the electric dipole (ED) interaction. We derived a simple formula for the ED interaction energy under an extended dipole approximation and clarified the ED contribution in the MC J aggregate.

リンク情報
DOI
https://doi.org/10.1103/PhysRevLett.94.136404
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000228289000038&DestApp=WOS_CPL
ID情報
  • DOI : 10.1103/PhysRevLett.94.136404
  • ISSN : 0031-9007
  • eISSN : 1079-7114
  • Web of Science ID : WOS:000228289000038

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