2005年4月
Determination of a merocyanine J-aggregate structure and the significant contribution of the electric dipole interaction to the exciton band wavelength
PHYSICAL REVIEW LETTERS
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- 巻
- 94
- 号
- 13
- 開始ページ
- pp136404 1-136404 4
- 終了ページ
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1103/PhysRevLett.94.136404
- 出版者・発行元
- AMER PHYSICAL SOC
The molecular alignment of a merocyanine (MC) J-aggregate monolayer at the air-water interface was determined by a grazing incidence x-ray diffraction method. The obtained molecular arrangement apparently shows that the conventional formula, which accounts only for the transition dipole interaction, is not sufficient to figure out the exciton band wavelength, suggesting the importance of the electric dipole (ED) interaction. We derived a simple formula for the ED interaction energy under an extended dipole approximation and clarified the ED contribution in the MC J aggregate.
- リンク情報
- ID情報
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- DOI : 10.1103/PhysRevLett.94.136404
- ISSN : 0031-9007
- eISSN : 1079-7114
- Web of Science ID : WOS:000228289000038