論文

2022年1月1日

Worrisome Exaggeration of Activity of Electrocatalysts Destined for Steady-State Water Electrolysis by Polarization Curves from Transient Techniques

Journal of The Electrochemical Society
  • Sengeni Anantharaj
  • ,
  • Subrata Kundu
  • ,
  • Suguru Noda

169
1
開始ページ
014508
終了ページ
014508
記述言語
掲載種別
研究論文(学術雑誌)
DOI
10.1149/1945-7111/ac47ec
出版者・発行元
The Electrochemical Society

Cyclic and linear sweep voltammetry techniques substantially misjudge the performance of water splitting electrocatalysts due to their transient nature that forbids the interface from reaching a steady-state. This misjudgment leads to the potentially detrimental yet unwittingly falsified data accumulation in the literature that requires immediate attention. Alternatively, sampled-current voltammetry (SCV) constructed from steady-state responses is advised to be widely adopted for screening electrocatalysts that are actually destined for steady-state operations. To show that this exaggeration is universal, a well-characterized activated SS, coprecipitated Co(OH)2, and Pt foil electrodes are studied for OER and HER in 1.0 M KOH. The results urge that it is time to adopt a relatively more precise alternative technique such as SCV.

リンク情報
DOI
https://doi.org/10.1149/1945-7111/ac47ec
URL
https://iopscience.iop.org/article/10.1149/1945-7111/ac47ec
URL
https://iopscience.iop.org/article/10.1149/1945-7111/ac47ec/pdf
ID情報
  • DOI : 10.1149/1945-7111/ac47ec
  • ISSN : 0013-4651
  • eISSN : 1945-7111

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