論文

2021年2月18日

H<inf>2</inf>-Free Selective Dehydroxymethylation of Primary Alcohols over Palladium Nanoparticle Catalysts

ChemCatChem
  • Sho Yamaguchi
  • ,
  • Hiroki Kondo
  • ,
  • Kohei Uesugi
  • ,
  • Katsumasa Sakoda
  • ,
  • Koichiro Jitsukawa
  • ,
  • Takato Mitsudome
  • ,
  • Tomoo Mizugaki

13
4
開始ページ
1135
終了ページ
1139
記述言語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/cctc.202001866

The dehydroxymethylation of primary alcohols is a promising strategy to transform biomass-derived oxygenates into hydrocarbon fuels. In this study, a novel, highly efficient, and reusable heterogeneous catalyst system was established for the H -free dehydroxymethylation of primary alcohol using cerium oxide-supported palladium nanoparticles (Pd/CeO ). A wide range of aliphatic and aromatic alcohols including biomass-derived alcohols were converted into the corresponding one-carbon shorter hydrocarbons in high yields in the absence of any additives, accompanied by the production of H and CO. Pd/CeO was easily recovered from the reaction mixture and reused, retaining its high activity, thus, providing a simple and sustainable methodology to produce hydrocarbon fuels from biomass-derived oxygenates. 2 2 2 2

リンク情報
DOI
https://doi.org/10.1002/cctc.202001866
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85098202451&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85098202451&origin=inward
ID情報
  • DOI : 10.1002/cctc.202001866
  • ISSN : 1867-3880
  • eISSN : 1867-3899
  • SCOPUS ID : 85098202451

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