2021年2月18日
H<inf>2</inf>-Free Selective Dehydroxymethylation of Primary Alcohols over Palladium Nanoparticle Catalysts
ChemCatChem
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- 巻
- 13
- 号
- 4
- 開始ページ
- 1135
- 終了ページ
- 1139
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/cctc.202001866
The dehydroxymethylation of primary alcohols is a promising strategy to transform biomass-derived oxygenates into hydrocarbon fuels. In this study, a novel, highly efficient, and reusable heterogeneous catalyst system was established for the H -free dehydroxymethylation of primary alcohol using cerium oxide-supported palladium nanoparticles (Pd/CeO ). A wide range of aliphatic and aromatic alcohols including biomass-derived alcohols were converted into the corresponding one-carbon shorter hydrocarbons in high yields in the absence of any additives, accompanied by the production of H and CO. Pd/CeO was easily recovered from the reaction mixture and reused, retaining its high activity, thus, providing a simple and sustainable methodology to produce hydrocarbon fuels from biomass-derived oxygenates. 2 2 2 2
- リンク情報
- ID情報
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- DOI : 10.1002/cctc.202001866
- ISSN : 1867-3880
- eISSN : 1867-3899
- SCOPUS ID : 85098202451