2020年11月21日
Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H<inf>2</inf>pressure
Organic and Biomolecular Chemistry
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- 巻
- 18
- 号
- 43
- 開始ページ
- 8827
- 終了ページ
- 8833
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/d0ob01603a
Exploring novel catalysis by less common, metal-non-metal nanoalloys is of great interest in organic synthesis. We herein report a titanium-dioxide-supported nickel phosphide nanoalloy (nano-Ni2P/TiO2) that exhibits high catalytic activity for the deoxygenation of sulfoxides. nano-Ni2P/TiO2 deoxygenated various sulfoxides to sulfides under 1 bar of H2, representing the first non-noble metal catalyst for sulfoxide deoxygenation under ambient H2 pressure. Spectroscopic analyses revealed that this high activity is due to cooperative catalysis by nano-Ni2P and TiO2. This journal is
- リンク情報
- ID情報
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- DOI : 10.1039/d0ob01603a
- ISSN : 1477-0520
- PubMed ID : 33179696
- SCOPUS ID : 85096081362