2013年5月27日
Synthesis of highly distorted π-extended [2.2]metacyclophanes by intermolecular double oxidative coupling
Angewandte Chemie - International Edition
- ,
- ,
- 巻
- 52
- 号
- 22
- 開始ページ
- 5740
- 終了ページ
- 5743
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/anie.201301180
A strained relationship: Oxidation of dihydroxy-substituted acenes provides face-to-face [2.2]metacyclophane-like dimers (see scheme
Ored, Si of iPr 3Si groupsblue). The products exhibited highly distorted structures caused by steric repulsion. UV/Vis and electrochemical analysis revealed that the HOMO-LUMO gap was decreased upon dimerization. Copyright © 2013 WILEY-VCH Verlag GmbH &
Co. KGaA, Weinheim.
Ored, Si of iPr 3Si groupsblue). The products exhibited highly distorted structures caused by steric repulsion. UV/Vis and electrochemical analysis revealed that the HOMO-LUMO gap was decreased upon dimerization. Copyright © 2013 WILEY-VCH Verlag GmbH &
Co. KGaA, Weinheim.
- ID情報
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- DOI : 10.1002/anie.201301180
- ISSN : 1433-7851
- ISSN : 1521-3773
- ORCIDのPut Code : 12623678
- SCOPUS ID : 84878043271