論文

査読有り
2013年5月27日

Synthesis of highly distorted π-extended [2.2]metacyclophanes by intermolecular double oxidative coupling

Angewandte Chemie - International Edition
  • Yutaro Koyama
  • ,
  • Satoru Hiroto
  • ,
  • Hiroshi Shinokubo

52
22
開始ページ
5740
終了ページ
5743
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/anie.201301180

A strained relationship: Oxidation of dihydroxy-substituted acenes provides face-to-face [2.2]metacyclophane-like dimers (see scheme
Ored, Si of iPr 3Si groupsblue). The products exhibited highly distorted structures caused by steric repulsion. UV/Vis and electrochemical analysis revealed that the HOMO-LUMO gap was decreased upon dimerization. Copyright © 2013 WILEY-VCH Verlag GmbH &amp
Co. KGaA, Weinheim.

リンク情報
DOI
https://doi.org/10.1002/anie.201301180
URL
http://orcid.org/0000-0002-5321-2205
ID情報
  • DOI : 10.1002/anie.201301180
  • ISSN : 1433-7851
  • ISSN : 1521-3773
  • ORCIDのPut Code : 12623678
  • SCOPUS ID : 84878043271

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