2012年
Synthesis and oxidation of cyclic tetraindole
CHEMICAL SCIENCE
- ,
- ,
- 巻
- 3
- 号
- 2
- 開始ページ
- 524
- 終了ページ
- 527
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c1sc00665g
- 出版者・発行元
- ROYAL SOC CHEMISTRY
A cyclic indole tetramer has been synthesized via an iridium-catalysed C-H borylation-cross coupling sequence. The tetraindole has a highly distorted structure, but can be oxidized with bromine and water into a highly planar macrocycle. The oxidized macrocycle can capture metal ions in its inner cavity as a novel porphyrin analogue, accompanied by a significant colour change from purple to blue or black.
- リンク情報
- ID情報
-
- DOI : 10.1039/c1sc00665g
- ISSN : 2041-6520
- eISSN : 2041-6539
- ORCIDのPut Code : 12623689
- SCOPUS ID : 84855703266
- Web of Science ID : WOS:000298963300032