2012年5月
Synthesis of Oxygen-Substituted Hexa-peri-hexabenzocoronenes through Ir-Catalyzed Direct Borylation
ORGANIC LETTERS
- ,
- ,
- 巻
- 14
- 号
- 10
- 開始ページ
- 2472
- 終了ページ
- 2475
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ol300743f
- 出版者・発行元
- AMER CHEMICAL SOC
Direct C-H borylation of hexa-peri-hexabenzocoronenes (HBCs) has been achieved under iridium catalysis, which allows efficient synthesis of hydroxy-substituted HBCs by oxidation of the boryl groups. Further oxidation of dihydroxy HBC with phenyliodine bis(trifluoroacetate) (PIFA) afforded tetraoxo-substituted HBC without any regioisomers, which can be considered as a pi-extended quinone.
- リンク情報
- ID情報
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- DOI : 10.1021/ol300743f
- ISSN : 1523-7060
- eISSN : 1523-7052
- ORCIDのPut Code : 12623691
- SCOPUS ID : 84862094740
- Web of Science ID : WOS:000304129000012