論文

2014年10月

Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2=COCICH3

CHEMICAL PHYSICS LETTERS
  • Nobuaki Tanaka
  • ,
  • Yoshitaka Urashima
  • ,
  • Hiromasa Nishikiori

614
開始ページ
258
終了ページ
262
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.cplett.2014.09.053
出版者・発行元
ELSEVIER SCIENCE BV

The UV light-induced reactions of chloroacetone in a cryogenic Ar matrix were investigated using infrared spectroscopy. The photoinduced isomerisations of gauche-chloroacetone to syn-chloroacetone and hypochlorous acid 1-methylethenyl ester were confirmed by comparing the experimental and calculated spectra. In addition, the photolysis products were found to be CH2=C=O and a cyclopropanone center dot center dot center dot HCl complex. The cyclopropanone center dot center dot center dot HCl complex was further decomposed into CH2=CH2, CO and HCl. The hypochlorous acid 1-methylethenyl ester was further isomerized to 2-chloro-2-methyloxirane. (C) 2014 Elsevier B.V. All rights reserved.

Web of Science ® 被引用回数 : 1

リンク情報
DOI
https://doi.org/10.1016/j.cplett.2014.09.053
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000344429200049&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.cplett.2014.09.053
  • ISSN : 0009-2614
  • eISSN : 1873-4448
  • Web of Science ID : WOS:000344429200049

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