論文

査読有り
2018年9月

Profitable Mass-Production of Acid-Modified Recovered Resins for Value-Added Mechanical Recycling as a Compatibilizer for Composites

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
  • Yuta Sunaga
  • ,
  • Shinji Ogoe
  • ,
  • Kenji Aoki
  • ,
  • Hirokazu Ito
  • ,
  • Yoshikuni Teramoto

6
9
開始ページ
12110
終了ページ
12118
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/acssuschemeng.8b02431
出版者・発行元
AMER CHEMICAL SOC

To realize upgrade recycling of commodity-type polyolefin resins, acid modification with maleic anhydride (MAH) and organic peroxide was applied to polypropylene (PP)-rich commercial recovered resins provided by different manufacturers. Modification conditions were established in advance to achieve high MAH grafting level as well as thermal fluidity using a laboratory scale batch kneader. Mass production prototyping with a view of productivity of 100 kg/h was carried out using an anisotropic twin-screw extruder. Transmission electron microscopy demonstrated that different domain structures of the original recovered resins were homogenized by the acid modification process. To evaluate the performance of the obtained acid-modified recovered resins as a compatibilizer, wood/plastic composite (WPC) compounds were prepared by kneading together with wood flour and PP and examined for their mechanical properties. As a result, the bending and impact strengths improved 1.5 times and the tensile strength increased 1.3 times in comparison with those of the composites containing no compatibilizer. We also conducted in 1-t/day mass production prototyping of the WPC compounds using an existing commercial production facility. By estimating the manufacturing costs of the acid-modified recovered resins, the profitability of the production was confirmed.

リンク情報
DOI
https://doi.org/10.1021/acssuschemeng.8b02431
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000443924100111&DestApp=WOS_CPL
Scopus Url
http://www.scopus.com/inward/record.url?eid=2-s2.0-85052794415&partnerID=MN8TOARS
ID情報
  • DOI : 10.1021/acssuschemeng.8b02431
  • ISSN : 2168-0485
  • ORCIDのPut Code : 71051862
  • SCOPUS ID : 85052794415
  • Web of Science ID : WOS:000443924100111

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