2018年9月
Profitable Mass-Production of Acid-Modified Recovered Resins for Value-Added Mechanical Recycling as a Compatibilizer for Composites
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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- 巻
- 6
- 号
- 9
- 開始ページ
- 12110
- 終了ページ
- 12118
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acssuschemeng.8b02431
- 出版者・発行元
- AMER CHEMICAL SOC
To realize upgrade recycling of commodity-type polyolefin resins, acid modification with maleic anhydride (MAH) and organic peroxide was applied to polypropylene (PP)-rich commercial recovered resins provided by different manufacturers. Modification conditions were established in advance to achieve high MAH grafting level as well as thermal fluidity using a laboratory scale batch kneader. Mass production prototyping with a view of productivity of 100 kg/h was carried out using an anisotropic twin-screw extruder. Transmission electron microscopy demonstrated that different domain structures of the original recovered resins were homogenized by the acid modification process. To evaluate the performance of the obtained acid-modified recovered resins as a compatibilizer, wood/plastic composite (WPC) compounds were prepared by kneading together with wood flour and PP and examined for their mechanical properties. As a result, the bending and impact strengths improved 1.5 times and the tensile strength increased 1.3 times in comparison with those of the composites containing no compatibilizer. We also conducted in 1-t/day mass production prototyping of the WPC compounds using an existing commercial production facility. By estimating the manufacturing costs of the acid-modified recovered resins, the profitability of the production was confirmed.
- リンク情報
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- DOI
- https://doi.org/10.1021/acssuschemeng.8b02431
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000443924100111&DestApp=WOS_CPL
- Scopus Url
- http://www.scopus.com/inward/record.url?eid=2-s2.0-85052794415&partnerID=MN8TOARS
- ID情報
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- DOI : 10.1021/acssuschemeng.8b02431
- ISSN : 2168-0485
- ORCIDのPut Code : 71051862
- SCOPUS ID : 85052794415
- Web of Science ID : WOS:000443924100111