ARIGA Katsuhiko

J-GLOBAL         Last updated: Dec 18, 2018 at 16:16
 

Profile

Affiliation: World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS) & Graduate School of Frontier Sciences, The University of Tokyo


Address: 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
Tel: +81-29-860-4597; Fax: +81-29-860-4832
E-mail: ARIGA.Katsuhiko@nims.go.jp

Major Fields: Supramolecular Chemistry, Surface Science, and Nanomaterials

Biography:
1987 Master Degree (Tokyo Institute of Technology)
1990 Doctor Degree (Tokyo Institute of Technology)
1987-1992 Assistant Professor (Tokyo Institute of Technology)
1990-1992 Postdoctoral Researcher (University of Texas at Austin)
1992-1998 JST Group Leader (Supermolecules Project) and CREST Researcher
1998-2001 Associate Professor (Nara Institute of Science and Technology)
2001-2003 JST Group Leader (Nanospace Project)
2004- Director of Supermolecules Group, NIMS
2007- Principal Investigator, MANA, NIMS,
2017- Professor (University of Tokyo)


Editorial Activity:

Editor-in-Chief of Bulletin of Chemical Society of Japan
International Advisory Board of Angewandte Chemie International Edition
International Advisory Board of Chemistry An Asian Journal
Editorial Board Member of Advanced Materials
Editorial Board Member of Chemistry of Materials
Editorial Board Member of Langmuir (- 2014)
Editorial Board Member of ACS Applied Materials & Interfaces
Editorial Board Member of Appl. Mater. Today
Editorial Board Member of J. Inorg. Organomet. Polym. Mater.
Editorial Board Member of Green Energy Environ.
Executive Board Member of Small Methods
Advisory Editor of Japanese Journal of Applied Physics
Advisory Editor of Applied Physics Express
Advisory Board Member of Physical Chemistry Chemical Physics
Advisory Panel of Nanotechnology
Associate Editor of Physical Chemistry Chemical Physics (-2016)
Associate Editor of Science and Technology of Advanced Materials
Associate Editor of Journal of Oleo Science
Section Editor of Chemistry Letters (-2016)
Asian Editor of Journal of Nanoscience and Nanotechnology (-2016)
Asian Editor of Advanced Science Engineering and Medicine (-2016)
Asian Editor of Nanoscience and Nanotechnology Letters (-2016)

Awards and others:
2010 Nice-Step Researcher 2010 (National Institute of Science and Policy, Japan)
2011 ISCB Award for Excellence 2011 (Indian Society of Chemists and Biologists)
2014- World Economic Forum, Global Agenda Councils (Nanotechnology) Member
2015 Contribution Award, Japan Society of Coordination Chemistry (JSCC)
Fellow of The Royal Society of Chemistry
Highly Cited Researcher (Thompson Reuter) One of world’s most influential researchers.
Honorary Member of Materials Research Society of India (MRSI)
Member of World Economic Forum Expert Network

According to Web of Science
Number of Paper: > 600
Citation: > 30000
H-Index: 94
(April 2018, Web of Science)

Published Papers

 
Ishihara Shinsuke, Labuta Jan, Futera Zdenek, Mori Shigeki, Sato Hisako, Ariga Katsuhiko, Hill Jonathan P.
JOURNAL OF PHYSICAL CHEMISTRY B   122(19) 5114-5120   May 2018   [Refereed]
The use of chiral auxiliaries, which derivatize enantiomers to diastereomers, is an established technique for NMR spectro-scopic analysis of chirality and enantiomeric excess (ee). Here we report that some small prochiral molecules exhibit ee-depe...
大切なことは質問をやめないことだ!:日本の研究力は低下しているのか?
ARIGA, Katsuhiko
現代化学   2018(2018) 58-58   Sep 2018
日本の論文数低下を招く原因について解説
Ji Qingmin, Yamazaki Tomohiko, Sun Jiao, Gorecka Zaneta, Huang Nien-Chi, Hsu Shan-hui, Shrestha Lok Kumar, Hill Jonathan P., Ariga Katsuhiko
ACS APPLIED MATERIALS & INTERFACES   9(5) 4509-4518   Feb 2017   [Refereed]
Sponge-like porous silica nanosheets having nanometer thicknesses and possess pores whose diameters are on the hundreds-of-nanometers scale have been used as a novel carrier for molecular immobilization of different guests. The coating of porous s...
E. Yu. Kozhunova, Q. Ji, J. Labuta, I. R. Nasimova, E. E. Makhaeva, K. Ariga
EXPRESS POLYMER LETTERS   12(11) 1005-1013   Aug 2018   [Refereed]
The thermo-induced collapse of the microgels and subchain mobility were thoroughly investigated by means of proton nuclear magnetic resonance (1H NMR) spectroscopy, as well as scanning electron microscopy and dynamic light scattering. It was found...
大切なことは質問をやめないことだ!:研究テーマの決め方を教えてください。
ARIGA, Katsuhiko
現代化学   (9) 15-15   Aug 2018
研究テーマの決め方を通して新規な研究のアイデアの模索法などを解説
Rodrigo Magana J., Kolen'ko Yury V., Deepak Francis Leonard, Solans Conxita, Shrestha Rekha Goswami, Hill Jonathan P., Ariga Katsuhiko, Shrestha Lok Kumar, Rodriguez-Abreu Carlos
ACS APPLIED MATERIALS & INTERFACES   8(45) 31231-31238   Nov 2016   [Refereed]
Carbon nanofibers (CNFs) with high surface area (820 m2/g) have been successfully prepared by a nanocasting approach using silica nanofibers obtained from chromonic liquid crystals as a template.
Arthur D. Dysart, Xin Li Phuah, Lok Kumar Shrestha, Katsuhiko Ariga, Vilas G. Pol
CARBON   134 334-344   Aug 2018   [Refereed]
Lithium-ion storage in monodispersed submicron carbon spheres (SCS) is dependent on the inert atmosphere thermal treatment to the sonochemically formed polymeric spheres. Battery electrode comprising SCS shows a high initial capacity up to 861 and...
Sahoo Pathik, Shrestha Rekha Goswami, Shrestha Lok Kumar, Hill Jonathan P., Takei Toshiaki, Ariga Katsuhiko
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS   26(6) 1301-1308   Nov 2016   [Refereed]
We report a facile non-templated hydrothermal synthesis method for the production of nickel ferrite (NiFe2O4)/carbon nanotube nanocomposite comprised of oxidized multi-walled carbon nanotube (o-MWCNT) uniformly coated with nanoparticles of NiFe2O4...
Santosh Goskulwad, Duong Duc La, Mohammad Al Kobaisi, Sidhanath V. Bhosale, Vipul Bansal, Ajayan Vinu, Katsuhiko Ariga, Sheshanath V. Bhosale
SCIENTIFIC REPORTS   8 11220-1-11220-11   Jul 2018   [Refereed]
We report on the synthesis of naphthalenediimide appended Lglutamate (NDI-L-Glu) that self-assembles into chiral supramolecular structures under physiological conditions. Specifically, NDI-L-Glu shows a mixture of left- and righthanded helices und...
Ariga Katsuhiko, Li Junbai, Fei Jinbo, Ji Qingmin, Hill Jonathan P.
ADVANCED MATERIALS   28(6) 1251-1286   Feb 2016   [Refereed]
In this review, various examples of dynamic functional materials are presented from the atom/molecular-level to macroscopic dimensions. These systems, including atomic switches, molecular machines, molecular shuttles, motional crystals, metal-orga...
Makoto Komiyama, Taizo Mori, Katsuhiko Ariga
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   91(7) 1075-1111   Jul 2018   [Refereed]
Revisiting known concept with the nanoarchitectonics concept would have great meaning in unification of individual research disciplines into one key concept. In this review, we survey fundamentals and recent trends of the molecular imprinting appr...
Mizuki Tenjimbayashi, Hirokazu Komatsu, Masaaki Akamatsu, Waka Nakanishi, Koji Suzuki, Jonathan P. Hill, Seimei Shiratori, Katsuhiko Ariga
RSC ADVANCES   6(17) 14261-14265   Jan 2016   [Refereed]
In this paper, we report a system for determination of potassium in blood which has the additional advantage of being blood-fouling resistant. We have replaced the generally used poly(vinyl chloride) (PVC) with hydrophobic fluorinated poly(vinylid...
Huang Nien-Chi, Ji Qingmin, Yamazaki Tomohiko, Nakanishi Waka, Hanagata Nobutaka, Ariga Katsuhiko, Hsu Shan-hui
PHYSICAL CHEMISTRY CHEMICAL PHYSICS   17(38) 25455-25462   Sep 2015   [Refereed]
We employed a series of nanosheet networks to facilitate the delivery of naked plasmid DNA into human mesenchymal stem cells (hMSCs). By putting different chemicals into the reaction mixture for etching the silica glass, we were able to fabricate ...
Webre Whitney A., Hill Jonathan P., Matsushita Yoshitaka, Karr Paul A., Ariga Katsuhiko, D'Souza Francis
DALTON TRANSACTIONS   45(9) 4006-4016   Jan 2016   [Refereed]
Effects of macrocycle bromination on the structural, electrochemical and anion binding properties of 5,10,15,20-tetrakis(3,5-di-t-butyl-4-oxo-cyclohexa-2,5-dienylidene)porphyrinogen, OxP, are reported.
Taizo Mori, Hiroyuki Tanaka, Amit Dalui, Nobuhiko Mitoma, Kengo Suzuki, Mutsuyoshi Matsumoto, Nikhil Aggarwal, Archita Patnaik, Somobrata Acharya, Lok Kumar Shrestha, Hirotoshi Sakamoto, Kenichiro Itami, Katsuhiko Ariga
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   57(31) 9679-9683   Jul 2018   [Refereed]
We report a new bottom-up methodology for carbon nanosheet fabrication using a newly designed anisotropic carbon nanoring molecule, CPPhen. CPPhen was self-assembled at a dynamic air-water interface with a vortex motion to afford molecular nanoshe...
Shrestha Lok Kumar, Ji Qingmin, Mori Taizo, Miyazawa Kun'ichi, Yamauchi Yusuke, Hill Jonathan P., Ariga Katsuhiko
CHEMISTRY-AN ASIAN JOURNAL   8(8) 1662-1679   Aug 2013   [Refereed]
Recent developments in the assembly of the functional molecule fullerene (C60) in the bulk or at interfaces have allowed production of shape-controlled nano-to-micro sized objects, which can possess excellent optoelectronic properties enabling fab...
大切なことは質問をやめないことだ!:物体を切ったらそこはどうなっているの?:マクロとナノの切り口
ARIGA, Katsuhiko
現代化学   (8) 15-15   Jul 2018
高分子のひもを切断したらそこは分子的にはどうなのかという現象の解説から始めて、マクロな現象と分子メカニズムの関連や界面の重要性を解説した。
Ji Qingmin, Acharya Somobrata, Hill Jonathan P., Richards Gary J., Ariga Katsuhiko
ADVANCED MATERIALS   20(21) 4027-+   Nov 2008   [Refereed]
By using a self assembly route with careful choice of ligands, we have achieved tunable multidimensional assembly of quantum sized gold nanoparticles arranged in a broad range of configurations. Conceptually, the assemblies of nanoparticles mimic...
Kenji Aramaki, Kaoru Ooishi, Misaki Fujii, Katsuhiko Ariga, Lok Kumar Shrestha
LANGMUIR   34(29) 8670-8677   Jun 2018   [Refereed]
We demonstrate a novel charge-free reverse wormlike micelle (RWLM) consisting of a ternary mixture of nonionic amphiphilic block copolymer, fatty acid alkyl ester oil and water under ambient conditions. Nonionic amphiphile tetra-[poly(oxyethylene)...
Vinu Ajayan, Srinivasu Pavuluri, Balasubramanian Veerappan V., Ariga Katsuhiko, Mori Toshiyuki, Nemoto Yoshihiro
CHEMISTRY LETTERS   37(10) 1016-1017   Oct 2008   [Refereed]
Here we report for the first time on the preparation of well-ordered titanium substituted KIT-6 at low acid concentration using polymeric surfactant. The characterization results show that the pore diameter and the unit cell constant of Ti-KIT-6 i...
Gundam Sandeep Kumar, Rekha Goswami Shrestha, Qingmin Ji, Jonathan P. Hill, Katsuhiko Ariga, Somobrata Acharya, Lok Kumar Shrestha
PHYSICAL CHEMISTRY CHEMICAL PHYSICS   20(27) 18873-18878   Jun 2018   [Refereed]
A hierarchical heterostructure composed of silver nanoparticles (Ag-NPs: average diameter ~10 nm) on fullerene nanorods (FNRs: average length ~11 µm and average diameter ~200 nm) was fabricated using a simple solution route. It was used as an...
Hill Jonathan P., Palza Humberto, Alam Sher, Ariga Katsuhiko, Schumacher Amy Lea, D'Souza Francis, Anson Christopher E., Powell Annie K.
INORGANIC CHEMISTRY   47(18) 8306-8314   Sep 2008   [Refereed]
The crystal structures of several dinuclear complexes of manganese are reported, and the decomposition and analysis of the nanostructured products derived from them are presented. 1,4,7,10-Tetraazacyclododecane (cyclen) forms dinuclear complexes c...
Davide Stefani, Mickael Perrin, Cristian Gutiérrez-Cerón, Albert C. Aragonès, Jacqueline Labra-Muñoz, Rodrigo D. C. Carrasco, Yoshitaka Matsushita, Zdenek Futera, Jan Labuta, Thien H. Ngo, Katsuhiko Ariga, Ismael Díez-Pérez, Herre S. J. van der Zant, Diana Dulić, Jonathan P. Hill
CHEMISTRYSELECT   3(23) 6473-6478   Jun 2018   [Refereed]
A conformationally flexible calix[4]pyrrole possessing a conjugated electronic structure (an N-substituted oxoporphyrinogen (OxP) related to porphyrin) was used to investigate the influence of mechanical stretching on the single-molecule conductan...
Xie Yongshu, Hill Jonathan P., Schumacher Amy Lea, Sandanayaka Atula S. D., Araki Yasuyuki, Karr Paul A., Labuta Jan, D'Souza Francis, Ito Osamu, Anson Christopher E., Powell Annie K., Ariga Katsuhiko
JOURNAL OF PHYSICAL CHEMISTRY C   112(28) 10559-10572   Jul 2008   [Refereed]
A new class of multichromophoric host compounds capable of binding guest species through two-point coordinative interaction is reported. The hosts contain appended zinc porphyrin (ZnP) moieties connected covalently by acetylene linkages to a centr...
Hirotomo Nishihara, Mao Ohwada, Takuya Kamimura, Masato Nishimura, Hideki Tanaka, Shotaro Hiraide, Minoru T. Miyahara, Katsuhiko Ariga, Qingmin Ji, Jun Maruyama, Fumito Tani
CHEMICAL COMMUNICATIONS   54(56) 7822-7825   Jun 2018   [Refereed]
Induced-fit accommodation of a variety of gaseous molecules including non-polar molecules has been demonstrated in porphyrin-based supramolecular architectures for the first time. Moreover, the gas uptake behaviour can be modulated by the central ...
Oishi Yushi, Kato Takayuki, Narita Takayuki, Ariga Katsuhiko, Kunitake Toyoki
LANGMUIR   24(5) 1682-1685   Mar 2008   [Refereed]
Atomic force microscopic observations of (hydrocarbon guanidinium / fluorocarbon carboxylic acid) mixed monolayer revealed that a nanoscopic phase-separated structure was formed by combination of attractive interaction between the oppositely-charg...
Gaulthier Rydzek, Amir Pakdel, Agnieszka Witecka, Dayangku Noorfazidah Awang Shri, Fabien Gaudière, Valeria Nicolosi, Parvaneh Mokarian-Tabari, Pierre Schaaf, Fouzia Boulmedais, Katsuhiko Ariga
MACROMOLECULES   51(12) 4424-4434   Jun 2018   [Refereed]
Compact polyelectrolyte complexes (COPECs), also named Saloplastics, represent a new class of material with high fracture strain and self-healing properties. Here, COPEC based on poly(methacrylic acid) (PMAA) and poly(allylamine hydrochloride) (PA...
Nanostructured Microspheres of MnO2 by Room Temperature Solution Processing.
HILL, Jonathan, ALAM, Sher, ARIGA, Katsuhiko, Christopher E. Anson, Annie K. Powell
CHEMICAL COMMUNICATIONS   2008 383-385   Jan 2008   [Refereed]
Nanostructured microspheres of manganese oxide have been prepared by the solution processing of manganese (II) salts using 1,4,7,10-tetraazacyclododecane and utilizing a crystalline intermediate stage.
Ariga Katsuhiko, Hill Jonathan P., Lee Michael V., Vinu Ajayan, Charvet Richard, Acharya Somobrata
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS   9(1) 014109-1-014109-96   Jan 2008   [Refereed]
The controlled fabrication of nanometer-scale objects is without doubt one of the central issues in current science and technology. However, existing fabrication techniques suffer from several disadvantages including size-restrictions and a genera...
大切なことは質問をやめないことだ!:学会発表ってどうやったらうまくできるんですか? Ans. 聴衆を圧倒しよう!
ARIGA, Katsuhiko
現代化学   2018(6) 58-58   Jun 2018
学会における発表のノウハウについて解説
大切なことは質問をやめないことだ!どうしたら論文がアクセプトされるの?コツを教えてください。
ARIGA, Katsuhiko
現代化学   (7) 23-23   Jun 2018
論文審査の実情やそれを乗り切るコツについて解説
Katsuhiko Ariga
Biomaterials Fabrication and Processing Handbook   335-366   Mar 2008
In order to hybridize bio-functions with artificial materials, supermolecular approaches are known to produce fruitful results. Lipid bilayer membrane well mimics cell membranes and provide a nice medium for immobilization of both bio-related mat...
Sawant Dhanashri P., Justus Josena, Balasubramanian Veerappan V., Ariga Katsuhiko, Srinivasu Pavuluri, Velmathi Sivan, Halligudi Shivappa B., Vinu Ajayan
CHEMISTRY-A EUROPEAN JOURNAL   14(10) 3200-3212   Mar 2008   [Refereed]
Here we report for the first time on the preparation of SBA-15/TiO2 nanocomposites with the different loadings of Keggin-type 12-tungstophosphoric acid (TPA) nanocrystals in the mesochannels through a simple and effective vacuum impregnation metho...
Phenanthroline-fused Pyrazinacenes: One-Pot Synthesis, Tautomerization and a Ru(II)(2,2’-bpy)2 Derivative
Pavel Švec, Whitney A. Webre, Gary J. Richards, Jan Labuta, Yutaka Wakayama, David Miklík, Paul A. Karr, Toshiyuki Mori, Katsuhiko Ariga, Francis D'Souza, Jonathan P. Hill
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   2018(22) 2541-2548   Jun 2018   [Refereed]
We report the one pot synthesis of a phenanthroline-fused pyrazinacene derivative (6,13-Dihydrodipyrido[3,2-a:2
Ariga Katsuhiko, Nakanishi Takashi, Michinobu Tsuyoshi
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY   6(8) 2278-2301   Aug 2006   [Refereed]
Immobilization of biomaterials on artificial devices such as electrodes via thin film technology is one of the most powerful strategies for advanced bio-related functions. In this review, we focus on SAM, LB films, and LBL assemblies, and from the...
Ariga Katsuhiko, Vinu Ajayan, Ji Qingmin, Ohmori Osamu, Hill Jonathan P., Acharya Somobrata, Koike Jun, Shiratori Seimei
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   47(38) 7254-7257   Sep 2008   [Refereed]
We demonstrate the layer-by-layer assembly of mesoporous carbon onto a quartz crystal microbalance and the use of the resulting structure for in situ measurement of nonionic aqueous guests, with three novelties: (i) the first example of LbL assemb...
Vinu Ajayan, Justus Josena, Balasubramanian Veerappan Vaithilingam, Halligudi Shivappa Basappa, Ariga Katsuhiko, Mori Toshiyuki
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS   73(8-9) 1112-1124   Oct 2008   [Refereed]
Hexagonally ordered mesoporous AlSBA-15 with different nSi/nAl ratios have been hydrothermally synthesized using the non-ionic copolymer Pluronic P123 surfactant as the structure directing agent and characterized by XRD, N2 adsorption–desorp...
Julien Vieaud, Jie Gao, Jérémy Cane, Michel Stchakovsky, Aotmane En Naciri, Katsuhiko Ariga, Reiko Oda, Emilie Pouget, Yann Battie
JOURNAL OF PHYSICAL CHEMISTRY C   122(22) 11973-11984   May 2018   [Refereed]
In this paper, we explore the ability of ellipsometry to characterize colloidal suspensionscomposed of gold nanoparticle (Au NP) chains.
Mariusz Cierech, Izabela Osica, Adam Kolenda, Jacek Wojnarowicz, Dariusz Szmigiel, Witold Łojkowski, Krzysztof Kurzydłowski, Katsuhiko Ariga, Elżbieta Mierzwińska-Nastalska
NANOMATERIALS   8(5) 305-1-305-14   May 2018   [Refereed]
The aim of this study is to evaluate the selected properties of the new ZnO - PMMA nanocomposite biomaterial used in making dentures that may explain its antifungal properties.
動け!働け!普通の高分子たち
ARIGA, Katsuhiko
高分子   67(6) 316-316   May 2018
分子をどうやって動かすか?特別な構造によらず、一般の分子を動かす試みを展望。
大切なことは質問をやめないことだ!:自己組織化の過去・現在・未来が知りたい:どこまでが分子?どこからが生物?
ARIGA, Katsuhiko
現代化学   2018(5) 46-46   May 2018
自己組織化の歴史的背景と未来の課題について解説。特に、分子集合体から生物のような機能体が生まれる点について。
Lok Kumar Shrestha, Taizo Mori, Katsuhiko Ariga
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE   35 68-80   May 2018   [Refereed]
In this short review, we focus on the structural changes and related dynamic functions with the terminology of dynamic nanoarchitectonics. We will cover selected topics on supramolecular polymorphism, supramolecular differentiation and dynamic-mot...
Václav Březina, Shinsuke Ishihara, Jan Lang, Lenka Hanyková, Katsuhiko Ariga, Jonathan P. Hill, Jan Labuta
CHEMISTRYOPEN   7(5) 323-335   Apr 2018   [Refereed]
Herein, we modulate the chromic response of a highly colored tetrapyrrole macrocycle, namely, tetrakis(3,5-di-tert-butyl-4-oxocyclohexadien-2,5-yl)porphyrinogen (OxP) by structural modification. N-Benzylation at the macrocyclic nitrogen atoms lead...
Katsuhiko Ariga, Taizo Mori, Waka Nakanishi
CHEMISTRY-AN ASIAN JOURNAL   13(10) 1266-1278   Apr 2018   [Refereed]
ナノカーと分子マシンの最新動向について解説
Bhadra Pokharel, Lok Shrestha, Katsuhiko Ariga, Dhananjai Pandey
ENERGIES   11(4) 850-1-850-10   Apr 2018   [Refereed]
We demonstrate a novel (Pb0.50Ba0.50)ZrO3 (PBZ50) ceramics that exhibits a reentrant relaxor ferroelectric phase transition in an antiferroelectric-based perovskite system.
Katsuhiko Ariga, Shun Watanabe, Taizo Mori, Jun Takeya
NPG ASIA MATERIALS   10 90-106   Apr 2018   [Refereed]
A target of this review is soft 2D nanoarchitectonics. Scientific views on soft 2D nanomaterials are not fully established as compared with rigid 2D materials. We assemble recent examples of 2D nanoarchitectonic constructions of functional materia...
大切なことは質問をやめないことだ!:国の研究機関での研究とは?面白いの?
ARIGA, Katsuhiko
現代化学   (4) 67-67   Apr 2018
大学と国の研究機関の研究スタイルの違い、NIMS が行う連携大学院やインターンシップを通しての学生との研究、国際交流などについて解説
Qingmin Ji, Xu Qiao, Xinbang Liu, Hongbing Jia, Jong-Sung Yu, Katsuhiko Ariga
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   91(3) 391-397   Mar 2018   [Refereed]
Carbon capsules with mesoporous wall and hollow interior were used to fabricate the sensing thin films for volatile aromatic vapors. To grow the thin film based on convenient layer-by-layer (LbL) process, carbon capsules need precoating with surfa...
Sharali Malik, Felicite M Ruddock, Adam H Dowling, Kevin Byrne, Wolfgang Schmitt, Ivan Khalakhan, Yoshihiro Nemoto, Hongxuan Guo, Lok Kumar Shrestha, Katsuhiko Ariga, Jonathan P Hill
BEILSTEIN JOURNAL OF NANOTECHNOLOGY   9 801-808   Mar 2018   [Refereed]
We present a simple method to make large quantities of few-layer graphene (FLG) starting with commercially available multi-layer graphene (MLG). This FLG material was then used to fabricate graphene dental-polymer composites.
Sangita Karanjit, Masaya Kashihara, Atsushi Nakayama, Lok Kumar Shrestha, Katsuhiko Ariga, Kosuke Namba
TETRAHEDRON   74(9) 948-954   Mar 2018   [Refereed]
A palladium(0) nanocluster supported on hydrotalcite has been prepared and tested for the Suzuki coupling reaction. The prepared catalyst showed very efficient catalytic activity for cross coupling of iodo- and bromoarenes under very mild reaction...
大切なことは質問をやめないことだ!:論文ってどうやって読むんですか?どうやって読ませるんですか?
ARIGA, Katsuhiko
現代化学   2018(3) 59-59   Mar 2018
科学論文の重要な内容を迅速に読み解く技術と研究内容を読者に効率的に知らせる執筆術について学術的に解説
Indra Saptiama, Yusuf Valentino Kaneti, Hamid Oveisi, Yoshitaka Suzuki, Kunihiko Tsuchiya, Kimiko Takai, Takeji Sakae, Subrata Pradhan, Md. Shahriar A. Hossain, Nobuyoshi Fukumitsu, Katsuhiko Ariga, Yusuke Yamauchi
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   91(2) 195-200   Feb 2018   [Refereed]
In this work, we have prepared alumina-embedded mesoporous silica and investigated their molybdenum (Mo) adsorption properties.
Mao Li, Shusen Kang, Jia Du, Jian Zhang, Jinxin Wang, Katsuhiko Ariga
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   57(18) 4936-4939   Feb 2018   [Refereed]
In this paper, firstly, controllable one or both of C(3)-C(3') and C(6)-C(6') coupling reactions of carbazolyl. In a second approach, an identical monomer containing two carbazolyls is polymerized using chemical and electrochemical oxidizers, lead...
大切なことは質問をやめないことだ!:分子マシンやナノカーって役に立つんですか?
ARIGA, Katsuhiko
現代化学   2018(2) 25-25   Feb 2018
分子マシンやナノカーの仕組みや今後の応用について一般向けに解説
Mahmoud M.M. Ahmed, Toyoko Imae, Jonathan P. Hill, Yusuke Yamauchi, Katsuhiko Ariga, Lok Kumar Shrestha
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS   538 127-132   Feb 2018   [Refereed]
We report the effect of treatment at high temperature (2000 。�C) on the exfoliation of a graphene that had been prepared by amine-treatment of an FeCl3-graphite intercalation compound and by preheat-treatment at low temperature (900 。&#6553...
Partha Bairi, Tohru Tsuruoka, Somobrata Acharya, Qingmin Ji, Jonathan P. Hill, Katsuhiko Ariga, Yusuke Yamauchi, Lok Kumar Shrestha
MATERIALS HORIZONS   5(2) 285-290   Jan 2018   [Refereed]
We report the synthesis of new mesoporous crystalline fullerene (C70) cubes (MCFC) at liquid-liquid interface between tert-butyl alcohol (TBA) and a solution of C70 in mesitylene under mild heat treatment. The highly crystalline pore walls of MCFC...
Whitney A. Webre, Habtom B. Gobeze, Shuai Shao, Paul A. Karr, Katsuhiko Ariga, Jonathan P. Hill, Francis D’Souza
CHEMICAL COMMUNICATIONS   54(11) 1351-1354   Jan 2018   [Refereed]
A bis-crown ether-oxoporphyrinogen was newly synthesized and self-assembled concurrently with C60 alkyl ammonium cations at the crown ether sites and F- anions (through hydrogen bonding) at the oxoporphyrinogen core.
Katsuhiko Ariga
Materials Nanoarchitectonics   255-263   Jan 2018
センシングシステム構築のためのナノアーキテクトニクスによるアプローチについて概説
大切なことは質問をやめないことだ!:研究者って楽しいですか?
ARIGA, Katsuhiko
現代化学   562(1) 62-62   Jan 2018
科学者の立場から、科学研究の重要性やモチベーションの在り方について解説
Supramolecular Polymorphism, Differentiation, and Transformation: Supramolecular Systems with Living-Creature-Like Shape-Shifts
SHRESTHA, Lok Kumar, ARIGA, Katsuhiko
材料表面   3(1) 27-33   Jan 2018   [Refereed]
本稿では、生体が単一細胞から様々な形に分化し発展するという特異的な現象に着目し、分子の集合体超分子が多様な形を自発的に作りうる現象について、若干の例を挙げて解説
Flavien Sciortino, Gaulthier Rydzek, Fabien Grasset, Myrtil L. Kahn, Jonathan P. Hill, Soizic Chevance, Fabienne Gauffre, Katsuhiko Ariga
PHYSICAL CHEMISTRY CHEMICAL PHYSICS   20(4) 2761-2770   Dec 2017   [Refereed]
Hollow nanocapsules (named HybridosomesR) possessing a polymer/nanoparticles shell were used to covalently construct hybrid films in a one-pot fashion. Alkyne bearing organic/inorganic HybridosomesR were reticulated with azide bearing homobifuncti...
Qin Tang, Partha Bairi, Rekha Goswami Shrestha, Jonathan P. Hill, Katsuhiko Ariga, Haibo Zeng, Qingmin Ji, Lok Kumar Shrestha
ACS APPLIED MATERIALS & INTERFACES   9(51) 44458-44465   Dec 2017   [Refereed]
Fullerene C60 microbelts were fabricated using liquid-liquid interfacial precipitation method and converted into quasi 2D mesoporous carbon microbelts by heat-treatment at elevated temperatures of 900 and 2000 C. The carbon microbelts obta...
Yunqi Li, Haibo Tan, Toshiaki Takei, Md. Shahriar A. Hossain, Md. Tofazzal Islam, Saad M. Alshehri, Tansir Ahamad, Rahul R. Salunkhe, Subrata Pradhan, Joel Henzie, Yusuke Yamauchi, Katsuhiko Ariga
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   2017(45) 5413-5416   Dec 2017   [Refereed]
We describe a simple and versatile method to synthesize hollow carbon nanospheres (HCNs) loaded with well distributed metal nanoparticles (i.e., Ir-HCNs, MoO2-HCNs, and WO2/WO3-HCNs). This procedure uses the electrostatic interaction between negat...
Katsuhiko Ariga, Taizo Mori, Lok Kumar Shrestha
CHEMICAL RECORD   18(7-8) 676-695   Dec 2017   [Refereed]
In this article, our recent research results in materials development based on the nanoarchitectonics concept are summarized in two stories, (i) nanoarchitectonics from fullerenes as the simplest nano-units and (ii) dimension-dependent nanoarchite...
Jeonghun Kim, Jung Ho Kim, Katsuhiko Ariga
Joule   1(4) 739-768   Dec 2017   [Refereed]
In this review, we explain the classification and redox active organic groups of redox active polymers. In addition, the latest advances in redox active polymers and their promising application potential for ESSs are discussed with a specific focu...
Julia Preiß, Felix Herrmann-Westendorf, Thien H. Ngo, Todd Martínez, Benjamin Dietzek, Jonathan P. Hill, Katsuhiko Ariga, Mikalai M. Kruk, Wouter Maes, Martin Presselt
JOURNAL OF PHYSICAL CHEMISTRY A   121(45) 8614-8624   Nov 2017   [Refereed]
We focus in the present article on the determination of the UV-vis spectroscopic properties of the free-base NH-tautomers and the deprotonated form of a new amphiphilic meso-pyrimidinylcorrole that can assemble to supramolecular structures at hete...
Chao-Ting Huang, Lok Kumar Shrestha, Katsuhiko Ariga, Shan-hui Hsu
JOURNAL OF MATERIALS CHEMISTRY B   5(44) 8854-8864   Nov 2017   [Refereed]
In this study, we prepared water-dispersible graphene and graphene oxide, which are 2D nanomaterials with high conductivity and potential applications in neural tissue engineering. Moreover, we synthesized a new biodegradable waterborne polyuretha...
Indra Saptiama, Yusuf Valentino Kaneti, Yumi Suzuki, Yoshitaka Suzuki, Kunihiko Tsuchiya, Takeji Sakae, Kimiko Takai, Nobuyoshi Fukumitsu, Zeid Abdullah Alothman, Md. Shahriar A. Hossain, Katsuhiko Ariga, Yusuke Yamauchi
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   90(10) 1174-1179   Oct 2017   [Refereed]
In this study, we have prepared mesoporous alumina (MA) materials using a soft-templated approach. By changing the applied calcination temperatures, the mesostructural ordering, surface areas, and crystallinity of the MA materials can be varied.
Qin Tang, Shufang Zhang, Xinbang Liu, Masato Sumita, Shinsuke Ishihara, Harald Fuchs, Qingmin Ji, Lok Kumar Shrestha, Katsuhiko Ariga
PHYSICAL CHEMISTRY CHEMICAL PHYSICS   19(43) 29099-29105   Oct 2017   [Refereed]
Polycyclic aromatic compounds (naphthalene, anthracene and pyrene) have been intercalated into the superstructures of fullerene nanowhiskers, using a facile liquid–liquid interfacial precipitation (LLIP) method. Due to the interaction betwee...
We-Hyo Soe, Yasuhiro Shirai, Corentin Durand, Yusuke Yonamine, Kosuke Minami, Xavier Bouju, Marek Kolmer, Katsuhiko Ariga, Christian Joachim, Waka Nakanishi
ACS NANO   11(10) 10357-10365   Oct 2017   [Refereed]
The molecular conformation of a bisbinaphthyldurene (BBD) molecule is manipulated using an LT-UHV STM on an Au(111) surface. BBD has two binaphthyl groups at both ends connected to a central durene leading to anti/syn/flat conformers. The syn dime...
Geoffrey Lawrence, Palraj Kalimuthu, Mercy Benzigar, Kinnari J. Shelat, Kripal S. Lakhi, Dae-Hwan Park, Qingmin Ji, Katsuhiko Ariga, Paul V. Bernhardt, Ajayan Vinu
ADVANCED MATERIALS   29(42) 1702295-1-1702295-7   Sep 2017   [Refereed]
We report the preparation of nanoporous protein films containing cytochrome C molecules through the soft templating strategy using polystyrene (PS) spheres of different sizes as templates.
You-Gui Huang, Shu-Qi Wu, Wei-Hua Deng, Gang Xu, Fa-Lu Hu, Jonathan P. Hill, Wei Wei, Sheng-Qun Su, Lok Kumar Shrestha, Osamu Sato, Ming-Yan Wu, Mao-Chun Hong, Katsuhiko Ariga
ADVANCED MATERIALS   29(42) 1703301-1-1703301-6   Sep 2017   [Refereed]
We report a metal-organic framework featuring fused Star of David catenanes. Two triangular metallacycles with opposite handedness are triply intertwined forming a Star of David catenane. Each catenane fuses with its six neighbors to generate a po...
Fu-Yu Hsieh, Lok Kumar Shrestha, Katsuhiko Ariga, Shan-hui Hsu
CHEMICAL COMMUNICATIONS   53(80) 11024-11027   Sep 2017   [Refereed]
Highly-aligned fullerene nanowhiskers (C60 NWs) are prepared by a modified liquid-liquid interfacial precipitation method. Neural stem cells on the aligned C60 NWs are oriented and have a high capacity to differentiate into mature neurons. The ali...
Makoto Komiyama, Keitaro Yoshimoto, Masahiko Sisido, Katsuhiko Ariga
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   90(9) 967-1004   Sep 2017   [Refereed]
In this review, we introduce two kinds of bio-related nanoarchitectonics, DNA nanoarchitectonics and cell-macromolecular nanoarchitectonics, both of which are basically controlled by chemical strategies.
Katsuhiko Ariga, David Tai Leong, Taizo Mori
ADVANCED FUNCTIONAL MATERIALS   28(27) 1702905-1-1702905-23   Sep 2017   [Refereed]
In this feature article, we introduce recent research activities regarding the development of advanced functional materials of hybrid and related architectures on the basis of nanoarchitectonics from diverse contexts of organic and inorganic mater...
Kosuke Minami, Taizo Mori, Waka Nakanishi, Narumi Shigi, Jun Nakanishi, Jonathan P. Hill, Makoto Komiyama, Katsuhiko Ariga
ACS APPLIED MATERIALS & INTERFACES   9(36) 30553-30560   Sep 2017   [Refereed]
We demonstrate the regulation of myogenic differentiation on fluid substrates by using a liquid–liquid interface as a scaffold. C2C12 myoblast cells were cultured using water-perfluorocarbon (PFC) interfaces as the fluid microenvironment. We...
界面で働く分子マシン:分子ピンセットなどの手動操作
ARIGA, Katsuhiko
CSJ カレントレビュー26分子マシンの科学   149-155   Sep 2017
分子マシンの界面操作とその関連研究について解説
Chinnasamy Sengottaiyan, Ramasamy Jayavel, Partha Bairi, Rekha Goswami Shrestha, Katsuhiko Ariga, Lok Kumar Shrestha
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   90(8) 955-962   Aug 2017   [Refereed]
Binary nanocomposite materials comprising of cobalt oxide (Co3O4) nanocrystals embedded in reduced graphene oxide (RGO) sheet were fabricated using one -pot hydrothermal synthetic route without using any structure guiding surfactant.
T. H. Ngo, J. Labuta, G. N. Lim, W. A. Webre, F. D'Souza, P. A. Karr, J. E. M. Lewis, J. P. Hill, K. Ariga, S. M. Goldup
CHEMICAL SCIENCE   8(9) 6679-6685   Aug 2017   [Refereed]
Building on recent progress in the synthesis of functional porphyrins for a range of applictions using the Cu-mediated azide-alkyne cycloaddition (CuAAC) reaction, we describe the active template CuAAC synthesis of interlocked triazole functionali...
Izabela Osica, Antonio F. A. A Melo, Gaku Imamura, Kota Shiba, Qingmin Ji, Jonathan P Hill, Frank N Crespilho, Krzysztof J Kurzydłowski, Genki Yoshikawa, Katsuhiko Ariga
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY   17(8) 5908-5917   Aug 2017   [Refereed]
In this research, we have utilized hierarchically-structured, radially porous silica hollow spheres as a platform for hemoprotein self-assembly. Proteins adsorbed onto silica surfaces through electrostatic interactions remained intact and exhibite...
Partha Bairi, Kosuke Minami, Jonathan P. Hill, Katsuhiko Ariga, Lok Kumar Shrestha
ACS NANO   11(8) 7790-7796   Jul 2017   [Refereed]
We report production of highly crystalline fullerene C70 cubes possessing an open–hole structure at the center of each their faces by using a solution–based self–assembly strategy. The holes are isolated with a solid core at the ...
Taizo Mori, Hirokazu Komatsu, Naoki Sakamoto, Kengo Suzuki, Jonathan P. Hill, Mutsuyoshi Matsumoto, Hideki Sakai, Katsuhiko Ariga, Waka Nakanishi
PHYSICAL CHEMISTRY CHEMICAL PHYSICS   20(5) 3073-3078   Jul 2017   [Refereed]
Intramolecular rotation of molecules contained in a two dimensional monolayer or a three dimensional collapsed film at an air-water interface was investigated by in situ fluorescence spectroscopy of twisted intramolecular charge transfer (TICT) ty...
Jiao Sun, Xinbang Liu, Qin Tang, Jonathan P. Hill, Katsuhiko Ariga, Qingmin Ji
CHEMISTRYSELECT   2(20) 5793-5799   Jul 2017   [Refereed]
A network of silica nanosheets composed of nanosheets of several nanometers in thickness and containing pores, whose dimensions are on the hundreds-of-nanometers scale, exhibits morphological self-adjustment upon binding of nanoparticles at its su...
Kazuko Fujii, Jonathan P. Hill, Hideo Hashizume, Shuichi Shimomura, Katsuhiko Ariga, Toshihiro Ando
JOURNAL OF MATERIALS SCIENCE   52(20) 12156-12169   Jun 2017   [Refereed]
We have succeeded in loading a neutral zinc porphyrin derivative(ZnTPPder)into a layered inorganic-organic compound, despite the well-known difficulties associated with incorporation of neutral pigments into the interlayer spaces of layered materi...
Katsuhiko Ariga, Taizo Mori, Waka Nakanishi, Jonathan P. Hill
PHYSICAL CHEMISTRY CHEMICAL PHYSICS   19(35) 23658-23676   Jun 2017   [Refereed]
Recent research examples of nanoarchitectonics, molecular machines, DNA nanotechnology, and DNA origami are compared with respect to the type of surface used, i.e. solid surfaces vs. liquid surfaces, for future perspectives of interfacial physics ...
Masaaki Akamatsu, Hirokazu Komatsu, Atsuki Matsuda, Taizo Mori, Waka Nakanishi, Hideki Sakai, Jonathan P. Hill, Katsuhiko Ariga
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   90(6) 678-683   Jun 2017   [Refereed]
We have developed an optical imaging technique for cesium ions involving an optode system in environmental water. An optode membrane was prepared incorporating a calix[6]arene derivative, which showed excellent selectivity toward cesium ions in aq...
Takuya Sagami, Shota Umemoto, Yuhei O. Tahara, Makoto Miyata, Yusuke Yonamine, Daisuke Ishikawa, Taizo Mori, Katsuhiko Ariga, Hiroyuki Miyake, Satoshi Shinoda
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   90(6) 739-745   Jun 2017   [Refereed]
New amphiphilic transition metal complexes with helical structures self-assembled to form disk-like units in 20 wt% EtOH/water. d-d transition bands in the visible-near IR region were used to probe conformational changes during the assembly process.
Ali Hossain Khan, Srabanti Ghosh, Bapi Pradhan, Amit Dalui, Lok Kumar Shrestha, Somobrata Acharya, Katsuhiko Ariga
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   90(6) 627-648   Jun 2017   [Refereed]
This review highlights the recent progress in the synthesis of a variety of 2D nanomaterials and their applications in energy conversion and storage.
Jing Tang, Jie Wang, Lok Kumar Shrestha, Md. Shahriar A. Hossain, Zeid Abdullah Alothman, Yusuke Yamauchi, Katsuhiko Ariga
ACS APPLIED MATERIALS & INTERFACES   9(22) 18986-18993   May 2017   [Refereed]
A series of porous carbon spheres with precisely adjustable mesopores (4~16 nm), high specific surface area (SSA, ~2000 m2 g−1), and sub-micrometer particle size (~300 nm) have been synthesized through a facile co-assembly of diblock polymer micel...
Masanari Okuno, Daisuke Ishikawa, Waka Nakanishi, Katsuhiko Ariga, Taka-aki Ishibashi
JOURNAL OF PHYSICAL CHEMISTRY C   121(21) 11241-11250   May 2017   [Refereed]
Heterodyne-detected vibrationally electronically doubly resonant chiral sum frequency generation (HD-DR chiral SFG) spectra were observed for the first time on monolayers.
Shangbin Jin, Cuiling Li, Lok Kumar Shrestha, Yusuke Yamauchi, Katsuhiko Ariga, Jonathan P. Hill
ACS APPLIED MATERIALS & INTERFACES   9(22) 18782-18789   May 2017   [Refereed]
We report a new approach for the fabrication of hybrid titanium dioxide/carbon materials derived from a porous titanium coordination polymer composed of a catechol-substituted porphyrin and Ti4+. Titanium dioxide nanocrystals were formed distribut...
しぶとく発展する交互吸着法:Layer-by-Layer 技術の近年の展開
ARIGA, Katsuhiko
化学と工業   70(5) 424-426   May 2017
交互吸着法の近年の展開を解説した。
Bang Lin Li, Magdiel I. Setyawati, Linye Chen, Jianping Xie, Katsuhiko Ariga, Chwee-Teck Lim, Slaven Garaj, David Tai Leong
ACS APPLIED MATERIALS & INTERFACES   9(18) 15286-15296   Apr 2017   [Refereed]
Layer-by-layer self-assembled stacked Testudo-like MoS2 superstructures carrying cancer drugs are formed from nanosheets controllably assembled with sequence based DNA oligonucleotides. These superstructures can disassemble autonomously in respons...
Raja Pradhananga, Laxmi Adhikari, Rekha Shrestha, Mandira Adhikari, Rinita Rajbhandari, Katsuhiko Ariga, Lok Shrestha
C   3(2) 12-1-12-11   Apr 2017   [Refereed]
Wool carpet dye adsorption properties of nanoporous activated carbon materials (NCMs) prepared from agro-product, bamboo is reported. Bamboo cane powder was chemically activated with phosphoric acid at different temperatures (400, 500, and 600 &#6...
Lok Kumar Shrestha, Rekha Goswami Shrestha, Sahira Joshi, Rinita Rajbhandari, Nishanta Shrestha, Mandira Pradhananga Adhikari, Raja Ram Pradhananga, Katsuhiko Ariga
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS   27(Suppl 1) S48-S56   Apr 2017   [Refereed]
Nanoarchitectonics of nanoporous carbon materials (NCMs) derived from natural resource; Areca Catechu Nut (ACN) with enhanced electrochemical supercapacitance properties is reported.
Yanyi Zhao, Wenwu Li, Xiangfen Jiang, Fengqiong Li, Xin Li, Wei Zhang, Ji-Sen Jiang, Jian Liu, Katsuhiko Ariga, Ming Hu
ACS NANO   11(4) 3662-3670   Mar 2017   [Refereed]
We demonstrated that coordination polymers (CPs) nanoplates could stack together spontaneously upon drying of the slurry of the nanoplates. The stacked CPs nanoplates could work like polymeric adhesives. Versatile articles could be glued when the ...
Izabela Osica, Gaku Imamura, Kota Shiba, Qingmin Ji, Lok Kumar Shrestha, Jonathan P. Hill, Krzysztof J. Kurzydłowski, Genki Yoshikawa, Katsuhiko Ariga
ACS APPLIED MATERIALS & INTERFACES   9(11) 9945-9954   Mar 2017   [Refereed]
In this work, we present a novel hybrid nanosystem based on a highly networked silicate nanoarchitecture conjugated through covalent bonding to an organic functional molecule, a tetraphenylporphyrin derivative, and its metal complexes. The sensing...
Exploration of Molecular Function (Molecular Recognition and Molecular Machinery) beyond Molecular Design and Synthesis: Surface
ARIGA, Katsuhiko, NAKANISHI, Waka
有機合成化学協会誌   75(3) 219-227   Mar 2017   [Refereed]
機能分子(分子認識素子、分子マシンなど)の開発手法について新たな提言を行った。
Vladimir A. Vinokurov, Anna V. Stavitskaya, Yaroslav A. Chudakov, Evgenii V. Ivanov, Lok Kumar Shrestha, Katsuhiko Ariga, Yusuf A. Darrat, Yuri M. Lvov
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS   18(1) 147-151   Feb 2017   [Refereed]
We developed ceramic core-shell materials based on abundant halloysite clay nanotubes with enhanced heavy metal ions loading through Schiff-base binding.
Jia Liu, Qingmin Ji, Tsubasa Imai, Katsuhiko Ariga, Hideki Abe
SCIENTIFIC REPORTS   7 41773-1-41773-8   Feb 2017   [Refereed]
Herein, we report that sintering-resistant nanoparticle systems can be realized through a simple materials-design which maximizes the particle-to-particle traveling distance of neighbouring nanoparticles.

Books etc

 
Nanoarchitectonics Approach for Sensing
Katsuhiko Ariga
2018   
センシングシステム構築のためのナノアーキテクトニクスによるアプローチについて概説
界面で働く分子マシン:分子ピンセットなどの手動操作
ARIGA, Katsuhiko
2017   
分子マシンの界面操作とその関連研究について解説
Nanoarchitectonics of Biomimetic Membranes
ARIGA, Katsuhiko
2017   
ナノ建築法による生体模倣膜の作成と機能について解説した。
Silica Nanomaterials
Katsuhiko Ariga, Qingmin Ji
2016   
Fabrication of desired nanostructured materials has been paid much attention in biology, biochemistry, and pharmaceutical sciences. For these demands, nanostructured inorganic materials have to be more utilized in biological pharmaceutical fields....
Tautomerism
2016   
Oxoporphyrinogens and Pyrazinacenes の互変異性について最近の成果をまとめた。
カーボン材料(ゼオライト転写以外)
ARIGA, Katsuhiko
2016   
カーボンナノケージやナノカーボンの積層構造などのカーボンによるナノ空間材料の最近の例について論じた。
Supermolecules
ARIGA, Katsuhiko
2016   
We focus on supramolecular strategies mainly for drug delivery as typical examples of bio-related and/or biomolecule-included examples. Typical examples on drug delivery system (DDS) and related functions with standard host-guest complexes and mol...
未来の科学者のためのナノテクガイドブック
ARIGA, Katsuhiko, NAKAYAMA, Tomonobu
2016   
現役研究者が書く子供向けのナノテク啓蒙書
ナノ空間に何が期待できるか
ARIGA, Katsuhiko, YAMAUCHI, Yusuke
2016   
ナノやナノ空間に意義や機能について、一般向けに解説。
材料革命ナノアーキテクトニクス
ARIGA, Katsuhiko
2014   
ナノテクノロジーの次にくるものとしてのナノアーキテクトニクスを材料研究を例に取り解説した。一般向けの本。
人の手の力で薬物放出を制御するゲル材料
KAWAKAMI, Kohsaku, IZAWA, Hironori, ARIGA, Katsuhiko
2013   
近年、人の手で加えられるようなマクロな力で、分子レベルの相互作用を操作する研究が注目を集めている。人の手で分子レベルの構造変化を起こす材料を設計し、薬物分子との相互作用を制御できれば、使用環境に制約されることなく、患者が自分の意思で薬物投与できる担体を創製することができる。本稿では、人の手で加える力で薬物が放出されるゲル担体を紹介する
Chapter 5. Mesoporous Nanoarchitectonics
Ajayan Vinu*, Qingmin Ji, Jonathan P. Hill, Katsuhiko Ariga*
2012   
In this chapter, we introduce recent our innovations including carbon nanocage, mesoporous carbon nitride, mesoporous boron nitride, and their hierarchic assemblies.
Bioinspired Materials Chemistry: Organic-Inorganic Nanocomposites
Pilar Aranda, Francisco M. Fernandes, Bernd Wicklein, Eduardo Ruiz-Hitzky, HILL, Jonathan, ARIGA, Katsuhiko
2012   
有機ー無機ハイブリッド材料研究の進展を中心としてバイオインスパイア材料の研究の最近の展開を解説した。
Chapter 2. Supramolecular Materials Nanoarchitechtonics
Katsuhiko Ariga*, Gary J. Richards, Masaaki Akamatsu, Hironori Izawa, Jonathan P. Hill
2012   
In this chapter, we introduce several topics of our research concerning supramolecular materials nanoarchitectonics. These topics are roughly categorized into (i) molecular-level complexes and arrangement, (ii) self-Assembly for functional structu...
Novel Multilayer Thin Films: Hierarchic Layer-by-Layer (Hi-LbL) Assemblies
ARIGA, Katsuhiko, JI, Qingmin, HILL, Jonathan
2012   
The LbL technique can be used in the fabrication of functional hierarchic structures using pre-synthesized nanostructured objects. In this chapter, several examples for construction of hierarchic structures by LbL assembly are described. The relat...
化学テキストシリーズ:ナノテクノロジー
Hiroshi Imahori, Yoshihiko Kanemitsu, ARIGA, Katsuhiko
2010   
化学の教科書として「ナノテクノロジー」の基礎を解説した。
ナノポア材料の作成法と機能
ARIGA, Katsuhiko
2009   
ナノメートルサイズの孔を持つ多孔性材料の作成法と機能について解説した。
Supramolecular Chemistry -Fundamentals and Applications-
ARIGA, Katsuhiko, Toyoki Kunitake
2006   
超分子化学の基礎から応用までを網羅した英文教科書で、学部学生・大学院生、研究者を対象とするもの。シュプリンガー(Springer-Verlag)から刊行される。
NA
ARIGA, Katsuhiko
2005   
シクロデキストリンのように日常生活に浸透している超分子から、さまざまな集合体やカーボンナノチューブなど時代の先端を行く超分子までを、解説した一般書。非専門系の学生や中高生までを対象とした啓蒙書でもある。

Conference Activities & Talks

 
Basics and Tips for Effective Manuscript Preparation
ARIGA, Katsuhiko
CSJ化学フェスタ   23 Oct 2018   
学術論文の作成法などを科学的見地から解説
Langmuir protocol for molecular machine operation, nanocarbon synthesis & life regulation
ARIGA, Katsuhiko
International Workshop on Self-assembly and Hierarchical Materia   8 Oct 2018   
界面環境を用いた、分子マシンコントロール、ナノカーボン作成、細胞制御について最新の成果を発表。
Control of molecular machine, 2D material, and life at Langmuir interface
ARIGA, Katsuhiko
Tsukuba Global Science Week (TGSW) symposium   22 Sep 2018   
液体界面を用いた分子マシン、ナノマテリアル、細胞分化の制御についての最近の成果を講演
Fullerene Nanoarchitectonics
SHRESTHA, Lok Kumar, ARIGA, Katsuhiko
The 69th Divisional Meeting on Colloid and Interface Chemistry   18 Sep 2018   
Dimensionally-integrated self-assembled fullerene crystals have received considerable interest for the possible applications in diverse fields including flexible optoelectronics device, field effect transistors, light emitting diodes, photov...
Fullerene Cubes with Micron-Size Pockets
SHRESTHA, Lok Kumar, ARIGA, Katsuhiko
The 69th Divisional Meeting on Colloid and Interface Chemistry   18 Sep 2018   
Atomic or molecular level manipulation has been well established and extensively studied using well–defined systems and various functional materials and nanosystems have been designed. However, manipulation of micron-sized hollow objects rem...
Manipulation of molecular macine and nanocar by nm-level tip approach and cm-size hand motion
ARIGA, Katsuhiko
2018 IEEE 8th International Conference NAP-2018   9 Sep 2018   
分子マシン・ナノカーの界面操作について、最新技術の展開を紹介
Photo-induced Charge Transfer and Photoswitching in Macrocycles and Supramolecular Manifolds
HILL, Jonathan, LABUTA, Jan, ISHIHARA, Shinsuke, Francis DSouza, ARIGA, Katsuhiko
7th EuCheMS Chemistry Congress   26 Aug 2018   
The assembly of organic chromophores will be discussed with emphasis on supramolecular effects. Porphyrins are widely used supramolecular components and we have developed systems used to probe photoinduced intramolecular processes of an oligochrom...
Self-assembly of Porphyrin and Heteroacene Organic Nanostructures
HILL, Jonathan, Yongshu Xie, David Miklik, S. Fatemeh Mousavi, AKADA, Misaho, WAKAYAMA, Yutaka, Thomas A. Jung, ARIGA, Katsuhiko
2nd World Congress on Nanoscience and Nanotechnology   10 Aug 2018   
Supramolecular arrangement of porphyrins and other molecules has great potential in the fields of molecular information storage and sensing due to their ease of deposition and good chemical and thermal stabilities. In particular, porphyrins of rel...
Manipulation of Molecular Machines with Dimension-Asymmetry at Interfaces
ARIGA, Katsuhiko
The 43rd International Conference on Coordination Chemistry   30 Jul 2018   
As use of cm-scale motion for control of molecular machines, we propose a novel methodology “hand-operating nanotechnology” where molecular orientation, organization and even functions in nanometer-scale can be operated by our macroscopic (hand) o...
Self-Assembled Fullerene Nanomaterials
SHRESTHA, Lok Kumar, GOSWAMI, Rekha, HILL, Jonathan, ARIGA, Katsuhiko
ICYS-WS 2018   4 Jul 2018   
Self-assembled fullerene (C60 or C70) nanostructures both in solution and on solid substrates have received considerable attention due to their potential applications in diverse fields including materials engineering and optoelectronic devic...
Sensing and Photochemistry in Oxoporphyrinogens
HILL, Jonathan, ISHIHARA, Shinsuke, LABUTA, Jan, Yongshu Xie, Francis DSouza, ARIGA, Katsuhiko
10th Intl Conf. on Porphyrins and Phthalocyanines   1 Jul 2018   
Oxoporphyrinogens are a class of porphyrinoid generally containing a tetrapyrrole macrocycle with oxo or oxocyclohexadienylidene groups substituted at their periphery. They are unique in that their physical structures are coupled to their electron...
ノーベル賞・ナノテクノロジーを超える界面超分子化学:分子マシンを手で動かす
ARIGA, Katsuhiko
第16回ホスト―ゲスト・超分子化学シンポジウム   2 Jun 2018   
界面超分子化学の最近の進展について招待講演
Fullerene Nanoarchitectonics: From Zero to Higher Dimensions
SHRESTHA, Lok Kumar, ARIGA, Katsuhiko
International Conference on Exploration in Physics (ICEP-2018)   29 May 2018   
We present a simple recipe of producing self-assembled fullerene C60 and C70 nano/microcrystals from zero to higher dimensions using solution based strategy called liquid-liquid interfacial precipitation (LLIP) method under mild conditions of temp...
Self-Assembled Fullerene Nanomaterials: From Zero to Higher Dimensions
SHRESTHA, Lok Kumar, ARIGA, Katsuhiko
International Conference of Layers, Films and Membranes   14 May 2018   
We present a simple recipe of producing self-assembled fullerene C60 and C70 nano/microcrystals from zero to higher dimensions using solution based strategy called liquid-liquid interfacial precipitation (LLIP) method under mild conditions of temp...
Chirality sensing, halochromism and solvatochromism in a conjugated calix[4]pyrrole
HILL, Jonathan, LABUTA, Jan, Vaclav Brezhina, ISHIHARA, Shinsuke, Lenka Hanykova, ARIGA, Katsuhiko
233rd ECS Meeting   13 May 2018   
The conjugated calix[4]pyrrole tetrakis(3,5-di-t-butyl-4-oxocyclohexadien-2,5-yl)porphyrinogen (OxP) is a highly coloured macrocycle with excellent potential as a sensing element in various applications. The first of these is chiral sensing where ...
Putting the N in ACENE
HILL, Jonathan, S. Fatemeh Mousavi, RICHARDS, Gary James, Thomas Jung, ARIGA, Katsuhiko, WAKAYAMA, Yutaka, Francis DSouza
7th UR1-CNRS-Saint-Gobain Workshop   27 Mar 2018   
Acenes are a class of unsaturated hydrocarbons which have found application as component materials in organic field effect transistors (OFETs) and organic thin film transistors (OTFTs). Pentacene (composed of five linearly annealated benzene rings...
Nanoarchitectonics for functional materials: Nanosheet-capsule, hole-in-cube, cube with antenna and so on
ARIGA, Katsuhiko, SHRESTHA, Lok Kumar
255th ACS National Meeting & Exposition   18 Mar 2018   
ナノアーキテクトニクスによる機能性ナノ構造開発について
Self-assembly of Porphyrin Nanostructures
HILL, Jonathan, AKADA, Misaho, WAKAYAMA, Yutaka, ARIGA, Katsuhiko
23rd Intl Conf. on Nanomaterials and Nanotechnology   15 Mar 2018   
Supramolecular arrangement of porphyrins and other molecules has great potential in the fields of molecular information storage and sensing due to their ease of deposition and good chemical and thermal stabilities. In particular, porphyrins of rel...
Conformation Manipulation and Motion of a Double Paddle Nanocar for the International Nanocar Race
We-Hyo Soe, SHIRAI, Yasuhiro, Corentin Durand, YONAMINE, Yusuke, MINAMI, Kosuke, Xavier Bouju, Marek Kolmer, ARIGA, Katsuhiko, JOACHIM, Christian, NAKANISHI, Waka
MANA International Symposium 2018   5 Mar 2018   
ナノカーレースや日本チームのナノカーについて,科学的重要な観点を解説し,結果を報告する
NMR chiral sensing based on prochiral molecules: Intermolecular transfer of magnetic anisotropy
ISHIHARA, Shinsuke, LABUTA, Jan, Hisako Sato, ARIGA, Katsuhiko, HILL, Jonathan
新学術領域「柔らかな分子系」第6回全体合宿会議   12 Dec 2017   
核磁気共鳴分光法(NMR)は、鏡像異性体(エナンチオマー)に対して同一のスペクトルを与えるため、NMRにてキラル分子の鏡像体過剰率を測定するためには、キラル分子から成る試薬を利用するなどして、鏡像異性体をジアステレオマーへと誘導することが定石である。一方、近年我々は、キラル分子から成る試薬を用いることなく、プロキラル分子を用いたNMRによる鏡像体過剰率の測定方法について提唱している。1,2 プロキラル分子は溶液中、早い交換過程の下でキラル分子を結合・脱離し、キラル分子の磁気異方性がプロキラ...
Porphyrin Clamp, Tripod and Rotor in Surface Assemblies
HILL, Jonathan, MISHRA, Puneet, UCHIHASHI, Takashi, ARIGA, Katsuhiko
Int. Conf. on Advances in Polymer Science and Technology   23 Nov 2017   
Supramolecular arrangement of porphyrins and other molecules has great potential in the fields of molecular information storage and sensing due to their ease of deposition and good chemical and thermal stabilities. In particular, porphyrins of rel...
Challenges for nanocar and molecular machine by nm-size tip approach and cm-level hand motion
ARIGA, Katsuhiko, NAKANISHI, Waka
International Symposium on Nanoscale Transport and phoTonics (IS   14 Nov 2017   
ナノカーや分子マシンの操作法について nm レベルのアプローチと cm レベルの操作について、最近の成果を報告する。
どうやって動かす分子マシン・ナノカー:超極小ナノ針で?自分たちの手で?
ARIGA, Katsuhiko
マテリアルズサイエンスノベーションの未来   28 Oct 2017   
分子マシン・ナノカーの操作法について、最新のナノテクを使う方法と界面科学を使う我々の独自法を解説
論文作成の基本とノウハウ,エディターからの助言
ARIGA, Katsuhiko
第7回CSJ化学フェスタ   17 Oct 2017   
最新の研究内容の紹介とともに論文作成法などについて解説する。
次元アシンメトリー場としての界面における分子マシン操作
ARIGA, Katsuhiko
第7回CSJ化学フェスタ   17 Oct 2017   
次元アシンメトリー場としての界面環境を用いた分子マシン操作について最近の成果を報告する。
What are necessary tools for control of molecular machines? nm-size STM Tip or cm-scale Hand Motion
ARIGA, Katsuhiko
ICFNN-2017   10 Oct 2017   
分子マシン・ナノカーの操作法について、非常に大きなサイズの違いで議論する。
Pyrazinacenes, Porphyrins and Oxoporphyrinogens
HILL, Jonathan, LABUTA, Jan, ISHIHARA, Shinsuke, MIKLIK, David, RICHARDS, Gary James, ARIGA, Katsuhiko
Int. Conf. on Functional Nanomaterials and Nanotechnology   10 Oct 2017   
Porphyrins substituted with antioxidant 2,6-di-tert-butylphenol substituents have been shown to exhibit different conformations based on the oxidation state of those substituents leading to the oxoporphyrinogens. On the other hand, pyrazinacenes a...
Hierarchically-Structured Fullerene Cubes with Sensing Antenna: Nanoarchitectonics from Zero to Higher Dimensions
SHRESTHA, Lok Kumar, GOSWAMI, Rekha, BAIRI, Partha, HILL, Jonathan, ARIGA, Katsuhiko
International Conference on Functional Materials and Nanotechnol   10 Oct 2017   
We present a simple recipe of producing self-assembled fullerene C60 and C70 nano/microcrystals from zero to higher dimensions using solution based strategy called liquid-liquid interfacial precipitation (LLIP) method under mild conditions of temp...
MSS感応膜の研究開発 ー その現状と未来
SHIBA, Kota, MINAMI, Kosuke, ARIGA, Katsuhiko
MEMSセンシング&ネットワークシステム展 2017   4 Oct 2017   
実用に耐える嗅覚IoTセンサの実現に向けては、多くの技術的課題が存在する。なかでも、標的分子(群)を高感度かつ選択的に測定する上で、センサ表面に塗布する感応膜の選択・設計が大変重要である。本講演では、我々が開発したセンサ素子MSSを中心に、その感応膜材料および評価手法の研究開発状況について概説する。また、未来型感応膜として、昆虫触角に似たナノ構造を有する感応膜材料などの開発についても紹介する。
超分子化学とマシン・ナノカー
ARIGA, Katsuhiko
公開講義「化粧品製剤学」   28 Sep 2017   
製剤にも関連する超分子化学とマシン・ナノカーの研究を一般向けに解説
Self-Assembled Fullerene Crystals at Liquid-Liquid Interface: From Zero to Higher Dimensions
SHRESTHA, Lok Kumar, GOSWAMI, Rekha, BAIRI, Partha, HILL, Jonathan, ARIGA, Katsuhiko
Tsukuba Global Science Week (TGSW) 2017   25 Sep 2017   
We present a simple recipe of producing self-assembled fullerene C60 and C70 nano/microcrystals from zero to higher dimensions using solution based strategy called liquid-liquid interfacial precipitation (LLIP) method under mild conditions of temp...
型にはまらないナノテクノロジー:ナノカーで世界で競う!あのノーベル賞の分子マシンを手で操る!
ARIGA, Katsuhiko
2017 IS&I 研究会   20 Sep 2017   
ナノカー・分子マシンの最近の研究について解説
ナノ薄膜上で情報変換デバイスを目指していたものが 分子マシン操作へと発展
ARIGA, Katsuhiko
第66回高分子討論会   20 Sep 2017   
分子デバイス作成から分子マシン操作に至る研究の推移を紹介
Pyrazinacenes and Oxoporphyrinogens
HILL, Jonathan, MIKLIK, David, MATSUSHITA, Yoshitaka, LABUTA, Jan, ARIGA, Katsuhiko
Congress of the Slovak Chemical Society   11 Sep 2017   
Porphyrins substituted with antioxidant 2,6-di-tert-butylphenol substituents have been shown to exhibit different conformations based on the oxidation state of those substituents leading to the oxoporphyrinogens. On the other hand, pyrazinacenes a...
Tunable biomolecular sensing by hand-operating nanotechnology
ARIGA, Katsuhiko
XVI Encontro da SBPMat/B-MRS Meeting   10 Sep 2017   
我々が独自に開発した界面での分子チューニング技術による生体分子の検出法について成果を報告する。
Handling Molecular Machines by our Hands Beyond Nobel Prize and Nanotechnology
ARIGA, Katsuhiko
XVI Encontro da SBPMat/B-MRS Meeting   10 Sep 2017   
分子マシン・ナノカーについての最新研究を紹介
Bitter Melon like mesoporous fullerene crystal design at liquid-liquid interface
Natsumi Furuuchi, GOSWAMI, Rekha, Yuji Yamashita, Tetsuji Hirao, ARIGA, Katsuhiko, SHRESTHA, Lok Kumar
The 68th Divisional Meeting on Colloid and Interface Chemistry   6 Sep 2017   
Self-assembled single crystalline fullerene nanostructures display excellent physicochemical and optoelectronic properties compared to the pristine fullerenes. They are promising materials in diverse fields such as material engineering, optoelectr...
Micron Size Dice-like Fullerene Crystals: Intentional Closing/Opening of Holes with Microscopic Recognition Properties
SHRESTHA, Lok Kumar, BAIRI, Partha, ARIGA, Katsuhiko
The 68th Divisional Meeting on Colloid and Interface Chemistry   6 Sep 2017   
Manipulation of micron-sized hollow objects remains a challenging task although the concept of atomic or molecular level manipulation has been established and extensively studied using well–defined systems and various functional materials an...
ナノアーキテクトニクスが拓く未来技術:原子スイッチ、ナノカーレース、人間の手で動かせる分子マシンなど
ARIGA, Katsuhiko
つくばサイエンス・アカデミー研究情報交換会セミナー   4 Sep 2017   
十億分の一のナノの世界を単に観察するだけではなく部品を組み立てるようにして新しい機能システムを作る、これがナノアーキテクトニクス(ナノ建築学)です。原子数個でパワーオンにできる原子スイッチと人間の脳のように記憶したり忘れたりするデバイス、分子の車が一千万分の一メートルの金のトラックを走って競争するナノカーレース、人間の手の動きで特定の分子をつかんだり放したりすることができる分子マシンなど、想像もしえないナノワールドの先端技術を紹介します。
Can we control molecular machines by our hands?
ARIGA, Katsuhiko
ChinaNANO 2017   29 Aug 2017   
We propose a novel methodology hand-operating nanotechnology where molecular orientation, organization and even functions in nanometer-scale can be operated by our macroscopic (hand) operation.
Mesoporous Fullerene Crystals Design at Liquid-Liquid Interface: From Zero to Higher Dimensions
SHRESTHA, Lok Kumar, GOSWAMI, Rekha, BAIRI, Partha, ARIGA, Katsuhiko
IUMRS-ICAM2017   27 Aug 2017   
Insertion of porous structures in the fullerene crystals is expected to increase the effective surface area drastically, which is expected to offer a great utility in many applications such as supercapacitors, large hydrogen storages, chemical and...
Mechanical Manipulation of Molecular Machines by Macroscopic Motions: Catch and release a molecule by our hands!
ARIGA, Katsuhiko
1st International Conference on Micro/Nanomachines   25 Aug 2017   
マクロスコピックな力学的刺激でナノマシンを操る技術について最近の成果を発表する。
ノーベル賞とナノテクノロジーを超える分子マシン操作法
ARIGA, Katsuhiko
日本化学会関東支部栃木地区講演会   9 Aug 2017   
昨年、分子マシンの基本概念がノーベル賞を受賞した。今、我々はナノテクノロジーの技術を駆使して分子マシンを操作しようとしている。そんな従来の概念を超えるものとして手で触って分子マシンを動かすという我々の新手法を紹介する。
Fullerene Nanoarchitectonics from Zero to Higher Dimensions
SHRESTHA, Lok Kumar, GOSWAMI, Rekha, BAIRI, Partha, HILL, Jonathan, ARIGA, Katsuhiko
ACCIS2017   8 Aug 2017   
We present a simple recipe of producing self-assembled fullerene C60 and C70 microcrystals from zero to higher dimensions using solution based strategy called liquid-liquid interfacial precipitation (LLIP) method under mild conditions of temperatu...
交互吸着法やセルフアッセンブリによる機能構造体の開発
ARIGA, Katsuhiko
高分子同友会講演会   2 Aug 2017   
機能分子はある構造に集合することによって新たな機能を発揮する。本講演では機能性物質をナノ薄膜として重ねていく交互吸着法や、分子が自発的に特定の構造体に集まるセルフアッセンブリなどの過程によるセンサーなど機能材料の開発を解説する。また、ノーベル賞のモレキュラーマシン(分子機械)やナノカー(分子の車)の操作法などの最新技術についても紹介する。
Manipulation of molecular machines and nanocars by cm-level hand-like motions? or nm-size tip approach?
ARIGA, Katsuhiko
I²CNER Seminar   4 Jul 2017   
分子マシンとナノカーの操作について最新成果を報告
Hand-Operating Nanotechnology: Manual Handling of Molecular Machines, DNAs and Cells at Dynamic Interfaces
ARIGA, Katsuhiko
2017 Liquid Crystals Gordon Research Conference   18 Jun 2017   
マクロスコピックな力学動作による分子マシン、DNA、細胞操作について、最近の成果を報告する。
Self-Assembled Fullerene Nanomaterials: From Zero to Higher Dimensions
SHRESTHA, Lok Kumar, BAIRI, Partha, GOSWAMI, Rekha, HILL, Jonathan, ARIGA, Katsuhiko
ICMAT2017   18 Jun 2017   
Self-assembled crystalline fullerenes (C60 or C70) nanostructures exhibit excellent physicochemical and optoelectronic properties including high electron mobility, high photosensitivity [1,2]. Owing to these appealing features together with excell...
分子マシン・ナノカーを操る方法:必要なものは nm サイズのチップか cm サイズの手か?
ARIGA, Katsuhiko
錯体化学若手の会   3 Jun 2017   
界面での分子マシン手動操作と STM チップによるナノカー駆動について解説する。
Pyrazinacenes and Oxoporphyrinogens
HILL, Jonathan, MIKLIK, David, Pavel Svec, MATSUSHITA, Yoshitaka, LABUTA, Jan, ISHIHARA, Shinsuke, Francis DSouza, ARIGA, Katsuhiko
231st ECS Meeting   28 May 2017   
Porphyrins substituted with antioxidant 2,6-di-tert-butylphenol substituents have been shown to exhibit different conformations based on the oxidation state of those substituents leading to the oxoporphyrinogens. On the other hand, pyrazinacenes a...
Nanostructured Polymeric Yolk-shell Capsules: a Versatile Tool for Hierarchical Nanocatalyst Design
ARIGA, Katsuhiko, SANCHEZ BALLESTER, Noelia Maria, RYDZEK, Gaulthier
EMRS   21 May 2017   
The concept of all-polymeric yolk-shell nanocapsules as a tunable platform for designing hierarchically nanostructured catalysts is demonstrated. Such nanocapsules are investigated for catalytic CO oxidation. Polyaniline yolk-shell nanocapsules ar...
How to control molecular machines by our hands: hand-operating nanotechnology
ARIGA, Katsuhiko
ACS Applied Materials & Interfaces Workshop   15 May 2017   
We propose a novel methodology “hand-operating nanotechnology”1,2) where molecular orientation, organization and even functions in nanometer-scale can be operated by our macroscopic (hand) operation. This concept can be realized at dynamic two-dim...
Fluorescence emission properties of a neutral porphyrin loaded into a layered inorganic-organic monolith
FUJII, Kazuko, HILL, Jonathan, HASHIZUME, Hideo, SHIMOMURA, Shuichi, ARIGA, Katsuhiko, ANDO, Toshihiro
SMS EUROPE 2017   26 Apr 2017   
Porphyrins are an important class of pigments found in almost all living systems. Their most significant roles involve either absorption of incident light, as in the chlorophylls and photosynthesis, and electrochemical processes including catalysi...
Colorimetric Sensor for Facile Identification of Methanol-Containing Gasoline
Noriko Shisa, Shinsuke Ishihara, Yougui Huang, Mikio Asai, Katsuhiko Ariga
2017 SAE World Congress   4 Apr 2017   
Despite methanol is toxic to human health and causes serious damage to automobile engine and components in fuel system, there are increasing distribution of methanol-containing gasoline in some area. Methanol demonstrates similar chemical properti...
We can operate molecular machines by our hands (Nobel Prize subjects)
ARIGA, Katsuhiko
Spring 2017– Functional Nanoassemblies   31 Mar 2017   
分子マシンの手動操作の革新的研究の紹介
Conformation manipulation of binaphthyl-dimer with a low temperature STM
We-Hyo Soe, Marek Kolmer, Xavier Bouju, SHIRAI, Yasuhiro, MINAMI, Kosuke, ARIGA, Katsuhiko, NAKANISHI, Waka
The Annual Spring meeting of the German Physical Society   19 Mar 2017   
One of the low temperature ultrahigh vacuum scanning tunneling microscope (STM) of the LT-UHV 4-STM has been used to study binaphthyl-dimer molecules on Au(111). The molecule has three C2 symmetry conformations energetically possible, namely, cis,...
Preparation of functional materials with a layered inorganic-organic monolith and their luminescence
FUJII, Kazuko, HILL, Jonathan, HASHIZUME, Hideo, SHIMOMURA, Shuichi, ARIGA, Katsuhiko, ANDO, Toshihiro
日本化学会第97春季年会   16 Mar 2017   
層状ケイ酸塩様の無機部分の層間に有機部分が存在し、無機部分と有機部分が共有結合して一体化した化合物(ここでは、層状無機-有機Monolithと呼ぶ)は、福嶋・谷らの先駆的な研究1)をはじめ、多数の研究が行われてきた。演者らも、層状ケイ酸塩様の無機部分と長鎖アルキルアンモニウム基が共有結合で一体化した層状無機-アルキルアンモニウムmonolith (PSAM)等を既に報告している2)。PSAMは、有機部分が容易に脱離しない、有機溶剤で膨潤する等の特徴がある。本研究では、PSAMを用いた機能性...
Bridging nanoscopic function with macroscopic action through interfacial synergy: hand-operation of molecular machine
ARIGA, Katsuhiko
日本化学会第97春季年会   16 Mar 2017   
界面シナジー効果を用いた分子マシン駆動について独自の成果を発表
Pyrazinacenes and Oxoporphyrinogens: Luck and Design in Chromophore Synthesis
HILL, Jonathan, RICHARDS, Gary James, Yongshu Xie, LABUTA, Jan, ARIGA, Katsuhiko
Collaborative Conf. on Organic Synthesis   13 Mar 2017   
Pyrazinacenes are a class of acene (e.g., pentacene) that contain two or more linearly-fused 1,4-pyrazine groups forming potentially n-type semiconducting materials. On the other hand, oxoporphyrinogens are a class of highly colored calix[4]pyrrol...
Preparation of hybrids of neutral pigments with layered inorganic-organic monolith and their emission
FUJII, Kazuko, HILL, Jonathan, HASHIZUME, Hideo, SHIMOMURA, Shuichi, ARIGA, Katsuhiko, ANDO, Toshihiro
5th Int'l conf on Multifuctional, Hybrid and Nanomaterials   6 Mar 2017   
Pigments have attractive properties especially with respect to the absorption of light involving their chromophore component. It ought to be advantageous to prepare materials with the pigments included in the solid-state. Layered materials possess...
Self-assembling pyrazinacenes: structure and properties
HILL, Jonathan, RICHARDS, Gary James, MIKLIK, David, LABUTA, Jan, Pavel Svec, ARIGA, Katsuhiko
OrgSyn50   26 Feb 2017   
Organic molecular materials have substantial potential for their application in electronic applications such as thin film transistors. The archetypal small molecular component is pentacene, an acene consisting of five linearly fused benzene rings....
CHIRAL SELF-ASSEMBLY OF PERYLENE DIIMIDES
ECHUE, Geraldine, ARIGA, Katsuhiko, HILL, Jonathan
8th International Conf. on Advanced Materials and Nanotechnology   12 Feb 2017   
A series of chiral perylene diimides (PDIs) has been prepared utilising amino acid-based substituents. By incorporating aminoacids, a library of molecular building blocks have been synthesized using a common structural scaffold, thus enabling ther...
Biodegradable, stretchable, transparent supramolecular networked films
PARKER, Helen Louise, ARIGA, Katsuhiko, HILL, Jonathan
8th International Conf. on Advanced Materials and Nanotechnology   12 Feb 2017   
Due to the increasing environmental burden created by non-biodegradable plastics alternative low-cost and environmentallybenign materials are fast required. One approach is to use natural structural materials such as the marine polysaccharidesalgi...
あの分子マシンを手で操って見せよう!誰でもできる有機分子に眠る機能を引き出す方法とは?
ARIGA, Katsuhiko
統合物質創成研究機構シンポジウム   26 Jan 2017   
近年、我々が独自に行っている界面技術による分子操作法について解説する。
あの分子マシンを手で操る Hand-Operating Nanotechnology
ARIGA, Katsuhiko
新学術領域研究「配位アシンメトリ」第2回 融合基礎・実習コース   12 Jan 2017   
分子マシンを手動で駆動する独自研究を紹介
Fullerene Nanoarchitectonics from Zero to Higher Dimensions
SHRESTHA, Lok Kumar, GOSWAMI, Rekha, BAIRI, Partha, HILL, Jonathan, ARIGA, Katsuhiko
ICOMEA Intl. Conference on Mater for Energy Applications 2017   3 Jan 2017   
elf-assembled single crystalline fullerenes (C60 or C70) nanostructures exhibit excellent physicochemical and optoelectronic properties including high electron mobility, high photosensitivity [1,2]. Owing to these appealing features together with ...
Porous Fullerene Nanomaterials: From Zero to Higher Dimensions
SHRESTHA, Lok Kumar, BAIRI, Partha, GOSWAMI, Rekha, ARIGA, Katsuhiko
26th Annual Meeting of MRS-J   19 Dec 2016   
Self-assembled single crystalline fullerenes nano/or microcrystals exhibit excellent physicochemical and optoelectronic properties including high electron mobility, high photosensitivity. Owing to these appealing features together with excellent e...
Hang-Operating Nanotechnology: Interfacial Magic for Molecular Manipulation
ARIGA, Katsuhiko
The 11th SPSJ International Polymer Conference (IPC2016)   13 Dec 2016   
界面における分子マニピュレーションの独自の技術を解説する。
Fullerene Nanoarchitectonics: From Zero to Higher Dimensions
SHRESTHA, Lok Kumar, BAIRI, Partha, GOSWAMI, Rekha, HILL, Jonathan, ARIGA, Katsuhiko
IUMRS-ICYRAM2016   11 Dec 2016   
In this contribution, we present a simple recipe of producing self-assembled nanostructures of fullerene C60 and C70 crystals from zero to higher dimensions using solution based strategy called liquid-liquid interfacial precipitation (LLIP) method...
Porphyrin Clamp, Tripod and Rotor in Surface Assemblies
HILL, Jonathan, Yongshu Xie, WAKAYAMA, Yutaka, MISHRA, Puneet, UCHIHASHI, Takashi, ARIGA, Katsuhiko
IUMRS-ICYRAM 2016   11 Dec 2016   
Supramolecular arrangement of porphyrins and other molecules has great potential in the fields of molecular information storage and sensing due to their ease of deposition and good chemical and thermal stabilities. In particular, porphyrins of rel...
Hang-Operating Nanotechnology: Can we control molecular machines by our hands?
ARIGA, Katsuhiko
HGI special seminar   21 Nov 2016   
マクロスコピックな動作ながらごく微小レベルの力で分子マシンを動かす技術を紹介する。
界面化学で分子に眠る機能を引き出す。そして分子マシンを手で操る
ARIGA, Katsuhiko
東京大学・物質系専攻特別セミナー   19 Nov 2016   
超分子相互作用に場の効果を考える、有機分子の構造を繊細にコントロールする、このようなことを考慮しないと、電子状態が鋭敏に変化し柔らかく動きうる有機分子の真の特性を引き出すことはできない。超分子化学と界面科学の融合は、柔らかい有機分子に眠る機能を引き出すことになる。
メタノール混合ガソリンの目視型簡易識別センサー
HUANG, Yougui, ISHIHARA, Shinsuke, ARIGA, Katsuhiko, Noriko Shisa
第25回ポリマー材料フォーラム   10 Nov 2016   
安価な石炭資源を背景として、メタノールを混合した自動車用ガソリンは中国で普及傾向にあり、今後世界的に拡大することが予想される。メタノールは有毒であり、エンジン性能への悪影響や燃料系部品の腐食も懸念されることから、日欧米の自工会はメタノールの使用に反対している。しかしながら、メタノールは、ガソリン添加材として既に普及しているエタノールと諸物性が酷似していることから、ユーザーがメタノール混合ガソリンを識別して、適切なガソリンを選択することは困難である。本研究では、メタノール混合ガソリンの使用自...
Transfer of Chiral Information via Soft Bonding: NMR Chiral Sensing Using an Acyclic Prochiral Probe
ISHIHARA, Shinsuke, LABUTA, Jan, ARIGA, Katsuhiko, HILL, Jonathan, Shigeki Mori, Hisako Sato
柔らかな分子系 第4回公開シンポジウム   27 Oct 2016   
核磁気共鳴分光法(NMR)は、鏡像異性体(R体およびS体)に対して同一のスペクトルを与えるため、キラルセンシングを行うためには、キラルなプローブ剤(例えばR’体)を結合させ、鏡像異性体をジアステレオマー(R+R’およびS+R’)へと誘導することが定石である。一方、我々は、ポルフィリンなどプロキラルな環状分子をプローブとして用い、キラルな酸などの光学純度を定量できることを示してきた1-4。ポルフィリンは、『柔らかい』非共有結合によって、キラルな分子との結合・解離を高速に繰り返しており、キラル...
Hand-Operating Nanotechnology: Low-Tech-Driven & Most-Energy-Efficient Molecular Material Process
ARIGA, Katsuhiko
IUMRS-ICA2016   20 Oct 2016   
A novel methodology “hand-operating nanotechnology” will be proposed. With this concept, molecular orientation, organization and even functions in nanometer-scale can be operated by our macroscopic (hand) operation. This concept can be realized at...
How can we control molecular machines by our hands? from Hand-Operating Nanotechnology to Functional Conformer Science
ARIGA, Katsuhiko
先端科学技術シンポジウム ー⾃⼰組織化と新しいナノ物   14 Oct 2016   
我々が独自に展開する Hand-Operating Nanotechnology と Functional Conformer Science について解説する。
Porous Fullerene Nanomaterials at Liquid-Liquid Interface
SHRESTHA, Lok Kumar, BAIRI, Partha, HILL, Jonathan, ARIGA, Katsuhiko
The 67th Divisional Meeting on Colloid and Interface Chemistry   22 Sep 2016   
Single crystalline fullerene crystal displays excellent physicochemical and optoelectronic properties including high electron mobility and high photosensitivity.1,2 Owing to these appealing features together with excellent electron accepting prope...
Emission from functional organometallic complex loaded into an alkylammonium derivative of a phyllosilicate
FUJII, Kazuko, HILL, Jonathan, HASHIZUME, Hideo, SHIMOMURA, Shuichi, ARIGA, Katsuhiko, ANDO, Toshihiro
第60回粘土科学討論会   15 Sep 2016   
 層状無機−有機複合体の研究は多数報告があり、層状の無機部分と層間に存在する有機部分が共有結合している複合体も福嶋・谷らの先駆的な研究1)を始め、多くの研究が行われてきた2)。演者らも、長鎖アルキルアンモニウム基が層状ケイ酸塩様部分と共有結合で一体化した複合体(ここでは、層状無機−アルキルアンモニウムmonolith(PSAM)と呼ぶ)等を既に報告している2)。有機部分が共有結合で強固に固定しているため容易には脱離しない。また、PSAMは有機溶剤で膨潤する。スメクタイトは陽イオン性の色素や...
Decomposition of Coordination Complexes for the Preparation of Nanostructured Materials
HILL, Jonathan, JIN, Shangbin, SHRESTHA, Lok Kumar, Wolfgang Schmitt, ARIGA, Katsuhiko
The 66th Conference of Japanese Society of Coordination Chemists   10 Sep 2016   
Controlling the morphology of nanostructured substances is an important method for producing materials with specific properties. In this work, we demonstrate that pristine crystalline coordination complexes of transition metal ions can be used as ...
Hand-Operating Nanotechnology: Innovative or Stupid Can we control molecular machines by our hands?
ARIGA, Katsuhiko
Québec City Convention Centre   7 Aug 2016   
マクロスコピックな力学動作で分子マシンを制御する世界唯一の技術を紹介する。
Hand-Operating Technology: How can we operate molecular machine by our hands?
ARIGA, Katsuhiko
Shandong University Seminar   15 Jul 2016   
力学駆動の分子操作技術について成果を講演
Hang-Operating Nanotechnology as Most Energy Efficient Technology for Real "Hand"ling of Molecular Machines
ARIGA, Katsuhiko
International Conference on Nanoenergy and Nanosystems 2016   13 Jul 2016   
われわれの進める「Hand-Operating Nanotechnology」を、非常に高効率の分子マシン駆動法として解説。
Sacrificial Rotaxane - Speed/Direction Control of Energy/Electron Transfer in Porphyrinoid Conjugates and Mechanical Picket Fence Synthesis
NGO, Thien Huynh, ARIGA, Katsuhiko, HILL, Jonathan
11th International Symposium on Macrocyclic and Supramolecular C   10 Jul 2016   
Corrole, a contracted porphyrin derivative lacking one carbon atom, shows similar structural and photophysical properties as porphyrin. By detailed molecular design, one can fine-tune these properties to control the interaction between corrole and...
Exploring the Potential of Supramolecular Porphyrinoid Conjugates in Various Research Fields
ARIGA, Katsuhiko, HILL, Jonathan, NGO, Thien Huynh
invited seminar   8 Jul 2016   
Due to its intrinsic properties, porphyrinoids have been of great interest in a wide range of research area, e.g. catalysis, photodynamic therapy, and molecular electronics… Within our research groups we are focusing on the construction of complex...
Exploring the Potential of Supramolecular Porphyrinoid Conjugates in Various Research Fields
NGO, Thien Huynh, ARIGA, Katsuhiko, HILL, Jonathan
Invited seminar   5 Jul 2016   
: Due to its intrinsic properties, porphyrinoids have been of great interest in a wide range of research area, e.g. catalysis, photodynamic therapy, and molecular electronics… Within our research groups we are focusing on the construction of compl...
Porphyrin Clamp and Tripod for Surface Assembly
HILL, Jonathan, XIE, Yongshu, AKADA, Misaho, WAKAYAMA, Yutaka, ARIGA, Katsuhiko
International Conference on Porphyrins and Phthalocyanines   3 Jul 2016   
Self-assembly of molecules implies intermolecular processes that can involve hydrogen bonding, van der Waals interactions (e.g. pi-pi stacking), amphiphilicity, coordination chemistry and combinations of these. Here, we will discuss assembly proce...
Sacrificial Rotaxane - When Copper Demetallation Fails toward Free Base Corrole Porphyrin Conjugates
NGO, Thien Huynh, ARIGA, Katsuhiko, HILL, Jonathan
9th International Conference on Porphyrins and Phthalocyanins   3 Jul 2016   
Corrole functionalization has provided a wide range of functional groups to corrole core, allowing the desired properties to be modified for different research fields. Copper center has been used as protecting group during the tedious synthetic pr...
How to control molecular machines, DNA origamis, and cell fates by our hands?
ARIGA, Katsuhiko
International Collaborative Seminar at the Institute of Process   9 Jun 2016   
分子マシン、DNA オリガミ、Cell 分化を手動同様の刺激でコントロールする手法について解説
Interactions of Antioxidant-Substituted Macrocycles
HILL, Jonathan, Daniel Payne, MATSUSHITA, Yoshitaka, JIN, Shangbin, LABUTA, Jan, ARIGA, Katsuhiko
229th Electrochemical Society Meeting   29 May 2016   
Porphyrins substituted with antioxidant 2,6-di-tert-butylphenol substituents have been shown to exhibit different conformations based on the oxidation state of those substituents leading to the oxoporphyrinogens. We have attempted to apply this fe...
Can we operate molecular machines by our hands? Hand-Operating Nanotechnology: World Stupidest Approach for Energy Most Efficient Molecular Manipulation
ARIGA, Katsuhiko
OIST Biomimetic Soft Matter Seminar   16 May 2016   
マクロスコピックな力学刺激による分子機能のコントロールについての成果を講演
World Stupidest Approach, Can we operate molecular machines by our hands? Hand-Operating Nanotechnology
ARIGA, Katsuhiko
Conference Advanced Material Scientific & Engineering Challenges   8 May 2016   
マクロスコピックな力学的駆動による分子捜査の新手法について報告する。
Hand-Operating Nanotechnology: Low-Tech-Driven Most-Energy-Efficient Molecular Technology
ARIGA, Katsuhiko
DGIST Semar   30 Mar 2016   
分子操作としての高効率新技術としての Hand-Operating Nanotechnology の成果を報告
Can we control molecular machines by our hands? Hand-Operating Nanotechnology makes it possible.
ARIGA, Katsuhiko
Chemistry Seminar   29 Mar 2016   
分子マシンコントロールの新技術について解説
Interaction between functional compounds and a phyllosilicate-organic hybrid with a covalent bond
FUJII, Kazuko, HILL, Jonathan, HASHIZUME, Hideo, SHIMOMURA, Shuichi, ARIGA, Katsuhiko, ANDO, Toshihiro
日本化学会第96回春季年会   24 Mar 2016   
層状ケイ酸塩様の無機部分と有機部分が共有結合した層状ケイ酸塩の有機誘導体は、既に報告されている。層状ケイ酸塩の有機誘導体は、比較的容易に層間に有機物を取り込む。このため、異なる色素が層間に共存したクマリン/シアニン共存系なども既に実現されている。本研究では、色素などの機能性物質と層状ケイ酸塩の有機誘導体との相互作用を調べたので、報告する。層状ケイ酸塩のアルキルアンモニウム誘導体(以下、ホスト複合体と呼ぶ)は、既報に従い合成した。次に、機能性物質の溶液を調製した。溶媒はトルエンやテトラヒドロ...
リン脂質より構成される多孔性固体粒子
KAWAKAMI, Kohsaku, ZHANG, Shaoling, FUKUSHIMA, Mayuko, SHRESTHA, Lok Kumar, ARIGA, Katsuhiko
日本化学会第96春季年会   24 Mar 2016   
リン脂質のみを用いて、多孔性固体粒子を調製する方法を確立した。本手法においてはリン脂質を混合溶媒に溶解し、相分離現象を利用して析出物を球形に生成したのち、凍結乾燥によって多孔性構造を与える。本粒子は二分子膜構造を持ち、親水性・疎水性両方の薬物を搭載できる。リポソームと相補的役割を担う新規薬物担体としての利用が期待される。
Energy efficient mechanical manipulation of molecular machines at interfaces
ARIGA, Katsuhiko
ICCMSE 2016   17 Mar 2016   
分子マシンを最も効率よく動かすのは力学的刺激であるという最近の成果を発表
階層的に集めるナノカーボン:アジャスタブルセンサーと細胞改変への道
ARIGA, Katsuhiko
フラーレン・ナノチューブ・グラフェンシンポジウム   20 Feb 2016   
フラーレン、グラフェン、メソポーラスカーボンカプセルを超分子集積化して作成する高感度センサーや細胞培養基材の開発について最近の成果を報告する。
Pyrazinacenes, porphyrins and nanoparticles: liquid crystals and self-assemblies
HILL, Jonathan, RICHARDS, Gary James, XIE, Yongshu, AKADA, Misaho, ACHARYA, Somobrata, ARIGA, Katsuhiko
EMN Meeting on Liquid Crystals   16 Feb 2016   
We introduce progress in the synthesis of liquid crystals containing N-analogues of pentacene. Also, some properties of liquid crystals doped with chalcogenide nanoparticles will be presented. For the porphyrins, self-assembly of implies intermole...
Hand-Operating Nanotechnology: Can we control molecules by our hands? Low-Tech-Driven Most-Energy-Efficient Molecular Technology
ARIGA, Katsuhiko
VISTEC Symposium   12 Feb 2016   
力学的に分子マシンを駆動することがエネルギー効率がk時和馬手高いプロセスであるという最近の発見を報告
Hand-Operating Nanotechnology: Can we control molecules by our hands? Low-Tech-Driven Most-Energy-Efficient Molecular Technology
ARIGA, Katsuhiko
Pure and Applied Chemistry International Conference 2016   9 Feb 2016   
近年、独自に進めている分子マニピュレーション技術について解説