2018年4月4日
A Spin-Active, Electrochromic, Solvent-Free Molecular Liquid Based on Double-Decker Lutetium Phthalocyanine Bearing Long Branched Alkyl Chains
Chemistry - An Asian Journal
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- 巻
- 13
- 号
- 7
- 開始ページ
- 770
- 終了ページ
- 774
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/asia.201800175
- 出版者・発行元
- John Wiley and Sons Ltd
Synthesis and characterization of a novel, multifunctional, solvent-free room-temperature liquid based on alkylated double-decker lutetium(III) phthalocyanine (Pc2Lu) are described. Lowering of the melting point and viscosity of intrinsically solid Pc2Lu compounds has been achieved through the attachment of flexible, bulky, and long branched-alkyl chains, that is, thio-2-octyldodecyl, to the periphery of the Pc2Lu unit. The embedded Pc2Lu unit maintains its inherent molecular functions, such as spin-active nature and electrochromic behavior in the liquid state. Comparison of the properties with a solid-like Pc2Lu derivative, functionalized with shorter alkyl chains, that is, thio-2-ethylhexyl, underlines the importance of the hampering effect on the π–π interactions of neighboring Pc2Lu molecules by bulkier and longer branched-alkyl chains. This study could possibly pave the way for novel multifunctional liquids whose spin-activities are associated with their rheological or optoelectronic properties.
- ID情報
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- DOI : 10.1002/asia.201800175
- ISSN : 1861-471X
- ISSN : 1861-4728
- ORCIDのPut Code : 42100353
- SCOPUS ID : 85042486980