2020年10月6日
Phosphine-oxide-catalyzed Enantioselective Cross-aldol Reactions of Aldehydes with Trichlorosilane as Lewis Acid Promoter
ChemCatChem
- ,
- ,
- ,
- 巻
- 12
- 号
- 19
- 開始ページ
- 4780
- 終了ページ
- 4783
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/cctc.202000914
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
A hypervalent silicon complex between trichlorosilane and a chiral phosphine oxide acts as an effective Lewis acid mediator that successfully promotes highly enantioselective cross-aldol reactions between two aldehydes. The high yielding transformation is realized with the assistance of triisobutylamine, which does not decompose trichlorosilane but rather converts the aldol donor into the silyl enol ether that undergoes the enantioselective cross-aldol reaction with a second aldehyde in combination with the chiral phosphine oxide catalyst.
- リンク情報
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- DOI
- https://doi.org/10.1002/cctc.202000914
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000565685800001&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85090184789&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85090184789&origin=inward
- ID情報
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- DOI : 10.1002/cctc.202000914
- ISSN : 1867-3880
- eISSN : 1867-3899
- SCOPUS ID : 85090184789
- Web of Science ID : WOS:000565685800001