論文

2020年10月6日

Phosphine-oxide-catalyzed Enantioselective Cross-aldol Reactions of Aldehydes with Trichlorosilane as Lewis Acid Promoter

ChemCatChem
  • Shunsuke Kotani
  • ,
  • Takuya Hanamure
  • ,
  • Yoshiki Mori
  • ,
  • Makoto Nakajima

12
19
開始ページ
4780
終了ページ
4783
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/cctc.202000914
出版者・発行元
WILEY-V C H VERLAG GMBH

A hypervalent silicon complex between trichlorosilane and a chiral phosphine oxide acts as an effective Lewis acid mediator that successfully promotes highly enantioselective cross-aldol reactions between two aldehydes. The high yielding transformation is realized with the assistance of triisobutylamine, which does not decompose trichlorosilane but rather converts the aldol donor into the silyl enol ether that undergoes the enantioselective cross-aldol reaction with a second aldehyde in combination with the chiral phosphine oxide catalyst.

リンク情報
DOI
https://doi.org/10.1002/cctc.202000914
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000565685800001&DestApp=WOS_CPL
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85090184789&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85090184789&origin=inward
ID情報
  • DOI : 10.1002/cctc.202000914
  • ISSN : 1867-3880
  • eISSN : 1867-3899
  • SCOPUS ID : 85090184789
  • Web of Science ID : WOS:000565685800001

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