2017年5月
pH-Dependent structural diversity of a 2-pyridinemethanol Cu complex and its relatively strong magnetic exchange coupling via hydrogen bonding
DALTON TRANSACTIONS
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- 巻
- 46
- 号
- 19
- 開始ページ
- 6196
- 終了ページ
- 6201
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c7dt00718c
- 出版者・発行元
- ROYAL SOC CHEMISTRY
The diversity of the self-assembled structures of a Cu complex via hydrogen bonding, including a square planar unit, is reported. The Cu complex forms two self-assembled structures by hydrogen bonding, depending on the acidity of the recrystallization conditions. A linear chain structure can be produced under acidic conditions, and a three-dimensional network structure is observed under basic conditions. The linear chain structure is constructed from intermolecular sharing of a hydrogen atom between two 2-pyridinemethanolate units, with an O...O distance of 2.412(1) angstrom and an O-H-O bond angle of 170(3)degrees. The linear chain structure exhibits relatively strong magnetic coupling (J = -9.91(2) cm(-1)) via hydrogen bonding between Cu atoms; this coupling was also confirmed by electron spin resonance experiments. Thermochromic behavior was also observed for the complex.
- リンク情報
- ID情報
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- DOI : 10.1039/c7dt00718c
- ISSN : 1477-9226
- eISSN : 1477-9234
- Web of Science ID : WOS:000401526700009