2014年12月
X-ray absorption fine structure imaging of inhomogeneous electrode reaction in LiFePO4 lithium-ion battery cathode
JOURNAL OF POWER SOURCES
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- 巻
- 269
- 号
- 開始ページ
- 994
- 終了ページ
- 999
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.jpowsour.2014.03.066
- 出版者・発行元
- ELSEVIER SCIENCE BV
To improve the performance of rechargeable lithium-ion batteries, a microscopic understanding of the electrochemical reaction at the cathode is necessary. The spatial distribution of the electrode redox reaction for the LiFePO4 cathode was analyzed by X-ray absorption fine structure (XAFS) imaging. Chemical state maps of the planar cathode electrode obtained by the in situ XAFS imaging revealed the inhomogeneity of the chemical state of Fe during the charge/discharge process. The chemical state maps for the reverse charge/discharge process demonstrated the reversibility of the inhomogeneous distribution. The in-plane radial progress of the reaction distribution strongly suggests that the inhomogeneous,electrode reaction is caused by the difference in electrical conductivity; the charging and discharging reactions proceed through reaction channels with low electrical resistance in the cathode. (C) 2014 Elsevier B.V. All rights reserved.
- リンク情報
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- DOI
- https://doi.org/10.1016/j.jpowsour.2014.03.066
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201402238260045324
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000340975200117&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-84907372187&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0002-1491-2647
- ID情報
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- DOI : 10.1016/j.jpowsour.2014.03.066
- ISSN : 0378-7753
- eISSN : 1873-2755
- J-Global ID : 201402238260045324
- ORCIDのPut Code : 42857562
- SCOPUS ID : 84907372187
- Web of Science ID : WOS:000340975200117