論文

査読有り
2006年10月

Constraint release in moderately entangled monodisperse star polyisoprene systems

MACROMOLECULES
  • Xiuying Qiao
  • ,
  • Toshiaki Sawada
  • ,
  • Yumi Matsumiya
  • ,
  • Hiroshi Watanabe

39
21
開始ページ
7333
終了ページ
7341
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ma0616155
出版者・発行元
AMER CHEMICAL SOC

For examination of a constraint release (CR) contribution to relaxation in monodisperse systems of moderately entangled six-arm star polyisoprenes (PI), viscoelastic measurements were conducted for blends of these star PI and a high molecular weight (M) linear PI. In the blends, the linear PI was dilute and entangled only with the matrix star chains. The terminal relaxation of this dilute linear probe occurred through competition of reptation and Rouse-type CR, as confirmed from its relaxation mode distribution. The probe relaxation time tau(probe) measured in the blends was utilized in the following way to elucidate the CR relaxation in the star matrices: Since the CR time tau(CR) of the star matrix is expressed as (2N(a))(2)tau(life) with 2N(a) and tau(life) being the entanglement number per two arms (span length) and the effective entanglement lifetime in the system, tau(CR) can be evaluated if the tau(life) value is known. For determination of the tau(life) value, the tau(probe) data of the linear probe in the star matrices was compared with the previously obtained tau(probe) data of the same probe in linear PI matrices under a molecular idea that tau(life) should be the same in a pair of star and linear matrices giving the same tau(probe) value. The molecular weight M-L,M-mat of the linear matrix paired with each star matrix was thus specified, and the value of tau(life) in the star matrix was determined by utilizing this M-L,M-mat value in a previously obtained empirical equation of tau(life) in the linear matrices ( tau(life) = 2.5 x 10(-18) M-L,mat(3) s at 40 degrees C). For the monodisperse systems of the star PI, the tau(CR) (=(2N(a))(2)tau(life)) thus evaluated was close to the measured relaxation time, indicating that the CR mechanism significantly contributes to the star relaxation. This result was in harmony with the validity of the molecular picture of partial dynamic-tube-dilation (p-DTD) confirmed for the star PI.

リンク情報
DOI
https://doi.org/10.1021/ma0616155
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000241106900025&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-33751329355&partnerID=MN8TOARS
ID情報
  • DOI : 10.1021/ma0616155
  • ISSN : 0024-9297
  • ORCIDのPut Code : 76272007
  • SCOPUS ID : 33751329355
  • Web of Science ID : WOS:000241106900025

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