論文

査読有り
2007年

Observation of phase separation with rheological measurement

NIHON REOROJI GAKKAISHI
  • Jun Takada
  • ,
  • Hiroshi Sasaki
  • ,
  • Yoshiaki Matsushima
  • ,
  • Akira Kuriyama
  • ,
  • Yumi Matsumiya
  • ,
  • Tadashi Inoue
  • ,
  • Hiroshi Watanabe

35
4
開始ページ
221
終了ページ
224
記述言語
日本語
掲載種別
研究論文(学術雑誌)
DOI
10.1678/rheology.35.221
出版者・発行元
SOC RHEOLOGY, JAPAN

We examined temperature(T)- and molecular weight(M)-dependent changes of the phase separated structure in immiscible polymer blends. Blend samples used were polyisoprene(PIP-H: Mw = 19.9x10(3); PIP-L: Mw = 14.4x10(3)) and polydimethylsiloxane(PDMS: Mw = 1.20x10(5)). The blend ratio was PIP/PDMS = 8/2(wt/wt). These blend samples included discrete phases(droplets) of PDMS and showed the relaxation much slower than the component relaxation. This relaxation reflected the shape recovery of the droplets, and the PIP/PDMS interfacial tension can be estimated with Palierne model. The interfacial tension decreased with increasing T, and this decrease was bigger for PIP-L than for PIP-H. These results agreed with the T and M dependencies of the UCST-type polymer-polymer compatibility.

リンク情報
DOI
https://doi.org/10.1678/rheology.35.221
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902257407231816
CiNii Articles
http://ci.nii.ac.jp/naid/10029818338
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000249638000007&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-36349028629&partnerID=MN8TOARS
ID情報
  • DOI : 10.1678/rheology.35.221
  • ISSN : 0387-1533
  • J-Global ID : 200902257407231816
  • CiNii Articles ID : 10029818338
  • ORCIDのPut Code : 76272192
  • SCOPUS ID : 36349028629
  • Web of Science ID : WOS:000249638000007

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