2007年
Observation of phase separation with rheological measurement
NIHON REOROJI GAKKAISHI
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- 巻
- 35
- 号
- 4
- 開始ページ
- 221
- 終了ページ
- 224
- 記述言語
- 日本語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1678/rheology.35.221
- 出版者・発行元
- SOC RHEOLOGY, JAPAN
We examined temperature(T)- and molecular weight(M)-dependent changes of the phase separated structure in immiscible polymer blends. Blend samples used were polyisoprene(PIP-H: Mw = 19.9x10(3); PIP-L: Mw = 14.4x10(3)) and polydimethylsiloxane(PDMS: Mw = 1.20x10(5)). The blend ratio was PIP/PDMS = 8/2(wt/wt). These blend samples included discrete phases(droplets) of PDMS and showed the relaxation much slower than the component relaxation. This relaxation reflected the shape recovery of the droplets, and the PIP/PDMS interfacial tension can be estimated with Palierne model. The interfacial tension decreased with increasing T, and this decrease was bigger for PIP-L than for PIP-H. These results agreed with the T and M dependencies of the UCST-type polymer-polymer compatibility.
- リンク情報
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- DOI
- https://doi.org/10.1678/rheology.35.221
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902257407231816
- CiNii Articles
- http://ci.nii.ac.jp/naid/10029818338
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000249638000007&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-36349028629&partnerID=MN8TOARS
- ID情報
-
- DOI : 10.1678/rheology.35.221
- ISSN : 0387-1533
- J-Global ID : 200902257407231816
- CiNii Articles ID : 10029818338
- ORCIDのPut Code : 76272192
- SCOPUS ID : 36349028629
- Web of Science ID : WOS:000249638000007