Mar, 2016
Electrocatalytic oxygen reduction on nitrogen-doped carbon nanoparticles derived from cyano-aromatic molecules via a solution plasma approach
CARBON
- ,
- ,
- Volume
- 98
- Number
- First page
- 411
- Last page
- 420
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1016/j.carbon.2015.11.013
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
Metal-free nitrogen-doped carbon nanoparticles (NCNPs) have been synthesized via a solution plasma process with the potential to achieve uniformly distributed nitrogen atoms. A set of cyano-aromatic molecules, including benzonitrile, 2-cyanopyridine, and cyanopyrazine, were used as a single-source precursor in the synthesis without the addition of a metal catalyst source. The resultant NCNPs reveal uniformly nanosized particles (20-40 nm) and an interconnected hierarchical pore structure with a high specific surface area (210-250 m(2) g(-1)). The difference in carbon/nitrogen mole ratios of organic precursors gives rise to the variation of nitrogen-doping level in NCNPs from 0.63 to 1.94 atom %. Detailed electrochemical evaluation toward the oxygen reduction reaction (ORR) demonstrates that NCNPs exhibit a significant improvement in terms of both onset potential and current density under alkaline and acidic conditions. The predominant distribution of graphitic-N and pyridinic-N sites on NCNPs plays an essential role in enhancing the ORR activity and the selectivity toward a four-electron reduction pathway. More importantly, NCNPs possess excellent robust long-term durability and strong methanol tolerance compared with those of a commercial Pt/carbon catalyst. (C) 2015 Elsevier Ltd. All rights reserved.
- Link information
- ID information
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- DOI : 10.1016/j.carbon.2015.11.013
- ISSN : 0008-6223
- eISSN : 1873-3891
- Web of Science ID : WOS:000367233000050