論文

査読有り
2017年3月

Charge Injection Mechanism at Heterointerfaces in CH3NH3PbI3 Perovskite Solar Cells Revealed by Simultaneous Time-Resolved Photoluminescence and Photocurrent Measurements

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
  • Taketo Handa
  • ,
  • David M. Tex
  • ,
  • Ai Shimazaki
  • ,
  • Atsushi Wakamiya
  • ,
  • Yoshihiko Kanemitsu

8
5
開始ページ
954
終了ページ
960
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/acs.jpclett.6b02847
出版者・発行元
AMER CHEMICAL SOC

Organic inorganic hybrid perovskite solar cells are attracting much attention due to their excellent photovoltaic properties. In these multilayered structures, the device performance is determined by complicated carrier dynamics. Here, we studied photocarrier recombination and injection dynamics in CH3NH3PbI3 perovskite solar cells using time-resolved photoluminescence (PL) and photocurrent (PC) measurements. It is found that a peculiar slowdown in the PL decay time constants of the perovskite layer occurs for higher excitation powers, followed by a decrease of the external quantum efficiency for PC. This indicates that a carrier injection bottleneck exists at the heterojunction interfaces, which limits the photovoltaic performance of the device in concentrator applications. We conclude that the carrier-injection rate is sensitive to the photogenerated carrier density, and the carrier-injection bottleneck strongly enhances recombination losses of photocarriers in the perovskite layer at high excitation conditions. The physical origin of the bottleneck is discussed based on the result of numerical simulations.

リンク情報
DOI
https://doi.org/10.1021/acs.jpclett.6b02847
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000395619100011&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/acs.jpclett.6b02847
  • ISSN : 1948-7185
  • Web of Science ID : WOS:000395619100011

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