2015年10月
Designs of Functional pi-Electron Materials based on the Characteristic Features of Boron
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
- ,
- 巻
- 88
- 号
- 10
- 開始ページ
- 1357
- 終了ページ
- 1377
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1246/bcsj.20150151
- 出版者・発行元
- CHEMICAL SOC JAPAN
Boron, a group 13 element, has several characteristic structural and electronic features: 1) trivalent boron compounds usually adopt a trigonal planar geometry; 2) due to the presence of a vacant p-orbital, effective orbital interaction with pi-conjugated compounds is possible; 3) the presence of a vacant p-orbital is furthermore responsible for high Lewis acidity; 4) the boryl group acts as a pi-electron-accepting group particularly in the excited state. The consequent exploitation of these characteristic features of boron in the molecular design enables us to produce sophisticated pi-functional materials with attractive photophysical and electronic properties. This account article illustrates our systematic studies on the molecular design and the development of functional pi-electron materials using boron as a key element.
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.20150151
- ISSN : 0009-2673
- eISSN : 1348-0634
- Web of Science ID : WOS:000362918900001