2015年
A unique Z-scheme 2D/2D nanosheet heterojunction design to harness charge transfer for photocatalysis
JOURNAL OF MATERIALS CHEMISTRY A
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- 巻
- 3
- 号
- 20
- 開始ページ
- 11006
- 終了ページ
- 11013
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c5ta01864a
- 出版者・発行元
- ROYAL SOC CHEMISTRY
Heterojunction photocatalysts could provide a potential strategy to solve the serious energy and environmental crises. However, the required heterojunction photocatalyts with high charge-separation efficiency and strong redox ability, which have unique dimensionality-dependent integrative and synergic effects, are intriguing but still underdeveloped. Here, for the first time, we design and fabricate 2D/2D heterojunctions between carbon nitride nanosheets and oxygen-vacancies confined in bismuth titanate mesoporous nanosheets. Especially, selective pollutant transformation of rhodamine B and 4-chlorophenol solutions under visible-light irradiation has been conducted by the use of 2D/2D heterojunction photocatalysts. Based on the steady-state and transient photoluminescence spectra and electron spin resonance technology, the Z-scheme energy-transfer mechanism is identified and the photogenerated charge carriers in the 2D/2D heterojunctions display a prolonged lifetime and higher separation compared to those in carbon nitride and bismuth titanate alone. This work will shed light on the rational design of more complex 2D/2D heterojunctions with accompanying applications in solar energy conversion and environmental remediation fields.
- リンク情報
- ID情報
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- DOI : 10.1039/c5ta01864a
- ISSN : 2050-7488
- eISSN : 2050-7496
- Web of Science ID : WOS:000354395400048