2019年
Gold(i)-catalyzed Nicholas reaction with aromatic molecules utilizing a bifunctional propargyl dicobalt hexacarbonyl complex
Organic & Biomolecular Chemistry
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回数 : 48
- ,
- ,
- ,
- 巻
- 17
- 号
- 37
- 開始ページ
- 8522
- 終了ページ
- 8526
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/C9OB01348B
- 出版者・発行元
- Royal Society of Chemistry ({RSC})
A benchtop-stable reagent for the catalytic Nicholas reaction was developed. By combining a propargyl dicobalt hexacarbonyl cluster with an ortho-alkynylbenzoate unit and a fluorous tag, introduction of a propargyl hexacarbonyl complex on various aromatic compounds having acid- or base-sensitive functional groups becomes possible by using a gold(I) catalyst. In addition, the presence of a fluorous tag facilitates convenient separation of the target products from byproducts.
- リンク情報
- ID情報
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- DOI : 10.1039/C9OB01348B
- ISSN : 1477-0520
- eISSN : 1477-0539
- ORCIDのPut Code : 59804248
- Web of Science ID : WOS:000487658900016