2017年9月21日
Synthesis and Characterization of Bioinspired [Mo<inf>2</inf>Fe<inf>2</inf>]–Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N<inf>2</inf>
Chemistry - A European Journal
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- 巻
- 23
- 号
- 53
- 開始ページ
- 13240
- 終了ページ
- 13248
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/chem.201702925
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
The hydride-supported [Mo Fe ] cluster complex {Cp*Mo(PMe )} {FeN(SiMe ) } (H) (2 a; Cp*=η -C Me ) and its [Mo Mn ] congener 2 b were synthesized from the reactions of Cp*Mo(PMe )(H) (1) with M{N(SiMe ) } (M=Fe, Mn). The amide-to-thiolate ligand-exchange reactions of complex 2 a with bulky thiol reagents (HSR; R=2,4,6-iPr C H (Tip), 2,6-(SiMe ) C H (Btp)) furnished the corresponding hydride-supported [Mo Fe ](SR) cluster complexes. The [Mo Fe ] clusters served as catalyst precursors for the reductive silylation of N and yielded ≈65–69 equivalents of N(SiMe ) relative to the [Mo Fe ] clusters. Treatment of complexes 2 a and b with an excess of CNtBu resulted in the formation of dinuclear Mo−Fe and Mo−Mn complexes, which indicated that the [Mo M ] cores (M=Fe, Mn) split into two dinuclear species upon accommodation of substrates. 2 2 3 2 3 2 2 8 5 5 2 2 3 5 3 2 2 3 6 2 3 2 6 3 2 2 2 2 2 2 3 3 2 2 2 2 5
- リンク情報
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- DOI
- https://doi.org/10.1002/chem.201702925
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/28685872
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000411357000037&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85028376529&origin=inward 本文へのリンクあり
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85028376529&origin=inward
- ID情報
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- DOI : 10.1002/chem.201702925
- ISSN : 0947-6539
- eISSN : 1521-3765
- PubMed ID : 28685872
- SCOPUS ID : 85028376529
- Web of Science ID : WOS:000411357000037