2013年
Synthesis of coordinatively unsaturated half-sandwich iron-silyl complexes with an N-heterocyclic carbene ligand and their reactions with H<inf>2</inf>
European Journal of Inorganic Chemistry
- ,
- ,
- 巻
- 2013
- 号
- 22-23
- 開始ページ
- 3966
- 終了ページ
- 3971
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/ejic.201300045
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
A half-sandwich, coordinatively unsaturated N-heterocyclic carbene complex of iron with a metallacycle was found to cleave the Si-H bonds of hydrosilanes to give 16-electron iron-silyl complexes. The reactions of silyl complexes with H led to the formation of dihydride complexes, in which hydride ligands weakly interact with the silicon atom. The molecular structures of these new complexes have been determined by means of X-ray crystallography. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. 2
- リンク情報
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- DOI
- https://doi.org/10.1002/ejic.201300045
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000329199900027&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84886507638&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=84886507638&origin=inward
- ID情報
-
- DOI : 10.1002/ejic.201300045
- ISSN : 1434-1948
- eISSN : 1099-0682
- SCOPUS ID : 84886507638
- Web of Science ID : WOS:000329199900027