論文

2008年9月3日

Reversible heterolysis of H<inf>2</inf> mediated by an M-S(Thiolate) bond (M = Ir, Rh): A mechanistic implication for [NiFe] hydrogenase

Journal of the American Chemical Society
  • Yasuhiro Ohki
  • ,
  • Mayumi Sakamoto
  • ,
  • Kazuyuki Tatsumi

130
35
開始ページ
11610
終了ページ
11611
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ja804848w
出版者・発行元
AMER CHEMICAL SOC

Facile H heterolysis was found to be mediated by coordinatively unsaturated Cp*Ir and Cp*Rh thiolate complexes. The reaction of iridium complex is reversible, and the formation of an intermediary Ir-H/thiol complex was detected. The reversible conversion between thiolate complex+H and hydride complex+thiol provides an intriguing functional model of [NiFe] hydrogenase. Copyright © 2008 American Chemical Society. 2 2

リンク情報
DOI
https://doi.org/10.1021/ja804848w
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/18683927
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000258792000024&DestApp=WOS_CPL
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=51349159182&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=51349159182&origin=inward
ID情報
  • DOI : 10.1021/ja804848w
  • ISSN : 0002-7863
  • PubMed ID : 18683927
  • SCOPUS ID : 51349159182
  • Web of Science ID : WOS:000258792000024

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