2008年9月3日
Reversible heterolysis of H<inf>2</inf> mediated by an M-S(Thiolate) bond (M = Ir, Rh): A mechanistic implication for [NiFe] hydrogenase
Journal of the American Chemical Society
- ,
- ,
- 巻
- 130
- 号
- 35
- 開始ページ
- 11610
- 終了ページ
- 11611
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja804848w
- 出版者・発行元
- AMER CHEMICAL SOC
Facile H heterolysis was found to be mediated by coordinatively unsaturated Cp*Ir and Cp*Rh thiolate complexes. The reaction of iridium complex is reversible, and the formation of an intermediary Ir-H/thiol complex was detected. The reversible conversion between thiolate complex+H and hydride complex+thiol provides an intriguing functional model of [NiFe] hydrogenase. Copyright © 2008 American Chemical Society. 2 2
- リンク情報
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- DOI
- https://doi.org/10.1021/ja804848w
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/18683927
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000258792000024&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=51349159182&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=51349159182&origin=inward
- ID情報
-
- DOI : 10.1021/ja804848w
- ISSN : 0002-7863
- PubMed ID : 18683927
- SCOPUS ID : 51349159182
- Web of Science ID : WOS:000258792000024