論文

査読有り
2010年11月

Generation of Stannabenzenes and Their Properties

ORGANOMETALLICS
  • Yoshiyuki Mizuhata
  • ,
  • Naoya Noda
  • ,
  • Norihiro Tokitoh

29
21
開始ページ
4781
終了ページ
4784
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/om100382n
出版者・発行元
AMER CHEMICAL SOC

Stannabenzenes 3, neutral stannaaromatic compounds having the simplest aromatic unit, were successfully generated by the reaction of the corresponding bromostannanes 5-Br with diisopropylamide mm, hexane at -40 degrees C. The generation of 3 was indicated by the formation of the [4 + 2] dimer 6 at room temperature. The thermal stability of 3 was completely different from that of the sila- and germabenzenes bearing the same substituent. The structural and electronic properties of stannabenzene were estimated by theoretical calculations.

リンク情報
DOI
https://doi.org/10.1021/om100382n
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000283572100017&DestApp=WOS_CPL
URL
http://orcid.org/0000-0001-5301-0024
ID情報
  • DOI : 10.1021/om100382n
  • ISSN : 0276-7333
  • ORCIDのPut Code : 30929563
  • Web of Science ID : WOS:000283572100017

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