2010年11月
Generation of Stannabenzenes and Their Properties
ORGANOMETALLICS
- ,
- ,
- 巻
- 29
- 号
- 21
- 開始ページ
- 4781
- 終了ページ
- 4784
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/om100382n
- 出版者・発行元
- AMER CHEMICAL SOC
Stannabenzenes 3, neutral stannaaromatic compounds having the simplest aromatic unit, were successfully generated by the reaction of the corresponding bromostannanes 5-Br with diisopropylamide mm, hexane at -40 degrees C. The generation of 3 was indicated by the formation of the [4 + 2] dimer 6 at room temperature. The thermal stability of 3 was completely different from that of the sila- and germabenzenes bearing the same substituent. The structural and electronic properties of stannabenzene were estimated by theoretical calculations.
- リンク情報
- ID情報
-
- DOI : 10.1021/om100382n
- ISSN : 0276-7333
- ORCIDのPut Code : 30929563
- Web of Science ID : WOS:000283572100017