2010年3月
Reactivity of an Aryl-Substituted Silicon-Silicon Triple Bond: Reactions of a 1,2-Diaryldisilyne with Alkenes
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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- 巻
- 132
- 号
- 8
- 開始ページ
- 2546
- 終了ページ
- +
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja9108566
- 出版者・発行元
- AMER CHEMICAL SOC
The reactivity of a bulky, diaryl-substituted disilyne, Ar-Si Si-Ar, was examined for the first time. Reaction of the disilyne with ethylene yielded an ethylene-bridged bis(silacyclopropane), which is interpreted as a Further reaction product of the initially formed 1,2-disilacyclobutene species with ethylene. A cyclohexane fused with a 1,2-disilacyclobutene was obtained in the reaction with cyclohexene. In the reaction with 2,3-dimethyl-1,3-butadiene, a tricyclo derivative was isolated from the complex product mixture.
- リンク情報
- ID情報
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- DOI : 10.1021/ja9108566
- ISSN : 0002-7863
- ORCIDのPut Code : 30929566
- Web of Science ID : WOS:000275117900028